Version · REACH
Version in force
Made by Regulation (EU) No 126/2013 32013R0126 on EUR-Lex (external, EUR-Lex)
Version 8 of 59 recorded for REACH.
First seen by emendrix on , when it first read this version; that is not a legal date.
1 change in this version
Consolidated versions 02006R1907-20121009 → 02006R1907-20130306. v1 is the previous version, v2 this one.
What changed
Annex XVII RESTRICTIONS ON THE MANUFACTURE, PLACING ON THE MARKET AND USE OF CERTAIN DANGEROUS SUBSTANCES, MIXTURES AND ARTICLES, Modified§
Explanation, written by a model and checked against the cited text
In entry 6 on asbestos fibres, the prohibition on manufacture, placing on the market and use is extended to cover mixtures containing these fibres added intentionally, in addition to articles containing them.
In entries 16 and 17 on lead carbonates and lead sulphates, the derogation wording is changed so that the reference to sulphates of lead in the ILO Convention 13 citation is dropped, the derogation is stated to cover the placing on the market for the restoration and maintenance use as well as the use itself, and a new requirement is added that a Member State using the derogation inform the Commission of it.
In the shared provision applying to entries 28 to 30, the reference to the concentration specified in Directive 1999/45/EC is qualified with the added phrase limiting it to cases where no specific concentration limit is set out in Part 3 of Annex VI to Regulation (EC) No 1272/2008; the remaining visible text is unchanged and the provided excerpt is truncated before further differences, if any, can be seen.
Cited: Annex XVII, v1 (external, EUR-Lex) · Annex XVII, v2 (external, EUR-Lex)
v1 is the previous version, v2 this one.
Each CAS and EC number in these tables links to its own page, which lists every entry that prints it across the acts this record holds.
0 entries added, 9 amended, 0 removed (1 of the amended differs only in spacing, dash forms or accents). 1 more changed only in whitespace and is not listed.
3 rows in the previous version and 6 in this one carry no key and are not compared.
9 entries amended
| Identifiers | Version | Column 1 Designation of the substance, of the group of substances or of the mixture | Column 2 Conditions of restriction |
|---|---|---|---|
| Entry 6CAS 12001-28-4CAS 12001-29-5CAS 12172-73-5CAS 132207-32-0CAS 77536-66-4CAS 77536-67-5CAS 77536-68-6 | Before | 6. Asbestos fibres (a) Crocidolite CAS No 12001-28-4 (b) Amosite CAS No 12172-73-5 (c) Anthophyllite CAS No 77536-67-5 (d) Actinolite CAS No 77536-66-4 (e) Tremolite CAS No 77536-68-6 (f) Chrysotile CAS No 12001-29-5 CAS No 132207-32-0 | 1. The manufacture, placing on the market and use of these fibres and of articles containing these fibres added intentionally is prohibited. However, Member States may exempt the placing on the market and use of diaphragms containing chrysotile (point (f)) for existing electrolysis installations until they reach the end of their service life, or until suitable asbestos-free substitutes become available, whichever is the sooner. By 1 June 2011 Member States making use of this exemption shall provide a report to the Commission on the availability of asbestos free substitutes for electrolysis installations and the efforts undertaken to develop such alternatives, on the protection of the health of workers in the installations, on the source and quantities of chrysotile, on the source and quantities of diaphragms containing chrysotile, and the envisaged date of the end of the exemption. The Commission shall make this information publicly available. Following receipt of those reports, the Commission shall request the Agency to prepare a dossier in accordance with Article 69 with a view to prohibit the placing on the market and use of diaphragms containing chrysotile. 2. The use of articles containing asbestos fibres referred to in paragraph 1 which were already installed and/or in service before 1 January 2005 shall continue to be permitted until they are disposed of or reach the end of their service life. However, Member States may, for reasons of protection of human health, restrict, prohibit or make subject to specific conditions, the use of such articles before they are disposed of or reach the end of their service life. Member States may allow placing on the market of articles in their entirety containing asbestos fibres referred to in paragraph 1 which were already installed and/or in service before 1 January 2005, under specific conditions ensuring a high level of protection of human health. Member States shall communicate these national measures to the Commission by 1 June 2011. The Commission shall make this information publicly available. 3. Without prejudice to the application of other Community provisions on the classification, packaging and labelling of substances and mixtures, the placing on the market and use of articles containing these fibres, as permitted according to the preceding derogations, shall be permitted only if suppliers ensure before the placing on the market that articles bear a label in accordance with Appendix 7 to this Annex. |
| After | 6. Asbestos fibres (a) Crocidolite CAS No 12001-28-4 (b) Amosite CAS No 12172-73-5 (c) Anthophyllite CAS No 77536-67-5 (d) Actinolite CAS No 77536-66-4 (e) Tremolite CAS No 77536-68-6 (f) Chrysotile CAS No 12001-29-5 CAS No 132207-32-0 | 1. The manufacture, placing on the market and use of these fibres and of articles and mixtures containing these fibres added intentionally is prohibited. However, Member States may exempt the placing on the market and use of diaphragms containing chrysotile (point (f)) for existing electrolysis installations until they reach the end of their service life, or until suitable asbestos-free substitutes become available, whichever is the sooner. By 1 June 2011 Member States making use of this exemption shall provide a report to the Commission on the availability of asbestos free substitutes for electrolysis installations and the efforts undertaken to develop such alternatives, on the protection of the health of workers in the installations, on the source and quantities of chrysotile, on the source and quantities of diaphragms containing chrysotile, and the envisaged date of the end of the exemption. The Commission shall make this information publicly available. Following receipt of those reports, the Commission shall request the Agency to prepare a dossier in accordance with Article 69 with a view to prohibit the placing on the market and use of diaphragms containing chrysotile. 2. The use of articles containing asbestos fibres referred to in paragraph 1 which were already installed and/or in service before 1 January 2005 shall continue to be permitted until they are disposed of or reach the end of their service life. However, Member States may, for reasons of protection of human health, restrict, prohibit or make subject to specific conditions, the use of such articles before they are disposed of or reach the end of their service life. Member States may allow placing on the market of articles in their entirety containing asbestos fibres referred to in paragraph 1 which were already installed and/or in service before 1 January 2005, under specific conditions ensuring a high level of protection of human health. Member States shall communicate these national measures to the Commission by 1 June 2011. The Commission shall make this information publicly available. 3. Without prejudice to the application of other Community provisions on the classification, packaging and labelling of substances and mixtures, the placing on the market and use of articles containing these fibres, as permitted according to the preceding derogations, shall be permitted only if suppliers ensure before the placing on the market that articles bear a label in accordance with Appendix 7 to this Annex. | |
| Entry 16CAS 1319-46-6CAS 598-63-0EC 209-943-4EC 215-290-6 | Before | 16. Lead carbonates: (a) Neutral anhydrous carbonate (PbCO3) CAS No 598-63-0 EC No 209-943-4 (b) Trilead-bis(carbonate)-dihydroxide 2Pb CO3-Pb(OH)2 CAS No 1319-46-6 EC No 215-290-6 | Shall not be placed on the market, or used, as substances or in mixtures, where the substance or mixture is intended for use as paint.
However, Member States may, in accordance with the provisions of International Labour |
| After | 16. Lead carbonates: (a) Neutral anhydrous carbonate (PbCO3) CAS No 598-63-0 EC No 209-943-4 (b) Trilead-bis(carbonate)-dihydroxide 2Pb CO3-Pb(OH)2 CAS No 1319-46-6 EC No 215-290-6 | Shall not be placed on the market, or used, as substances or in mixtures, where the substance or mixture is intended for use as paint. However, Member States may, in accordance with the provisions of International Labour Organization (ILO) Convention 13, permit the use on their territory of the substance or mixture for the restoration and maintenance of works of art and historic buildings and their interiors, as well as the placing on the market for such use. Where a Member State makes use of this derogation, it shall inform the Commission thereof. | |
| Entry 17CAS 15739-80-7CAS 7446-14-2EC 231-198-9EC 239-831-0 | Before | 17. Lead sulphates: (a) PbSO4 CAS No 7446-14-2 EC No 231-198-9 (b) Pbx SO4 CAS No 15739-80-7 EC No 239-831-0 | Shall not be placed on the market, or used, as substances or in mixtures, where the substance or mixture is intended for use as paint.
However, Member States may, in accordance with the provisions of |
| After | 17. Lead sulphates: (a) PbSO4 CAS No 7446-14-2 EC No 231-198-9 (b) Pbx SO4 CAS No 15739-80-7 EC No 239-831-0 | Shall not be placed on the market, or used, as substances or in mixtures, where the substance or mixture is intended for use as paint. However, Member States may, in accordance with the provisions of International Labour Organization (ILO) Convention 13, permit the use on their territory of the substance or mixture for the restoration and maintenance of works of art and historic buildings and their interiors, as well as the placing on the market for such use. Where a Member State makes use of this derogation, it shall inform the Commission thereof. | |
| Entry 28 | Before | 28. Substances which appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 classified as carcinogen category 1A or 1B (Table 3.1) or carcinogen category 1 or 2 (Table 3.2) and listed as follows: Carcinogen category 1A (Table 3.1)/carcinogen category 1 (Table 3.2) listed in Appendix 1 Carcinogen category 1B (Table 3.1)/carcinogen category 2 (Table 3.2) listed in Appendix 2 29. Substances which appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 classified as germ cell mutagen category 1A or 1B (Table 3.1) or mutagen category 1 or 2 (Table 3.2) and listed as follows: Mutagen category 1A (Table 3.1)/mutagen category 1 (Table 3.2) listed in Appendix 3 Mutagen category 1B (Table 3.1)/mutagen category 2 (Table 3.2) listed in Appendix 4 30. Substances which appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 classified as toxic to reproduction category 1A or 1B (Table 3.1) or toxic to reproduction category 1 or 2 (Table 3.2) and listed as follows: Reproductive toxicant category 1A adverse effects on sexual function and fertility or on development (Table 3.1) or reproductive toxicant category 1 with R60 (May impair fertility) or R61 (May cause harm to the unborn child) (Table 3.2) listed in Appendix 5 Reproductive toxicant category 1B adverse effects on sexual function and fertility or on development (Table 3.1) or reproductive toxicant category 2 with R60 (May impair fertility) or R61 (May cause harm to the unborn child) (Table 3.2) listed in Appendix 6 | Without prejudice to the other parts of this Annex the following shall apply to entries 28 to 30:
1. Shall not be placed on the market, or used,
as substances,
as constituents of other substances, or,
in mixtures,
for supply to the general public when the individual concentration in the substance or mixture is equal to or greater than:
either the relevant specific concentration limit specified in Part 3 of Annex VI to Regulation (EC) No 1272/2008, or,
the relevant concentration specified in Directive |
| After | 28. Substances which appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 classified as carcinogen category 1A or 1B (Table 3.1) or carcinogen category 1 or 2 (Table 3.2) and listed as follows: Carcinogen category 1A (Table 3.1)/carcinogen category 1 (Table 3.2) listed in Appendix 1 Carcinogen category 1B (Table 3.1)/carcinogen category 2 (Table 3.2) listed in Appendix 2 29. Substances which appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 classified as germ cell mutagen category 1A or 1B (Table 3.1) or mutagen category 1 or 2 (Table 3.2) and listed as follows: Mutagen category 1A (Table 3.1)/mutagen category 1 (Table 3.2) listed in Appendix 3 Mutagen category 1B (Table 3.1)/mutagen category 2 (Table 3.2) listed in Appendix 4 30. Substances which appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 classified as toxic to reproduction category 1A or 1B (Table 3.1) or toxic to reproduction category 1 or 2 (Table 3.2) and listed as follows: Reproductive toxicant category 1A adverse effects on sexual function and fertility or on development (Table 3.1) or reproductive toxicant category 1 with R60 (May impair fertility) or R61 (May cause harm to the unborn child) (Table 3.2) listed in Appendix 5 Reproductive toxicant category 1B adverse effects on sexual function and fertility or on development (Table 3.1) or reproductive toxicant category 2 with R60 (May impair fertility) or R61 (May cause harm to the unborn child) (Table 3.2) listed in Appendix 6 | Without prejudice to the other parts of this Annex the following shall apply to entries 28 to 30: 1. Shall not be placed on the market, or used, as substances, as constituents of other substances, or, in mixtures, for supply to the general public when the individual concentration in the substance or mixture is equal to or greater than: either the relevant specific concentration limit specified in Part 3 of Annex VI to Regulation (EC) No 1272/2008, or, the relevant concentration specified in Directive 1999/45/EC where no specific concentration limit is set out in Part 3 of Annex VI to Regulation (EC) No 1272/2008. Without prejudice to the implementation of other Community provisions relating to the classification, packaging and labelling of substances and mixtures, suppliers shall ensure before the placing on the market that the packaging of such substances and mixtures is marked visibly, legibly and indelibly as follows: Restricted to professional users. 2. By way of derogation, paragraph 1 shall not apply to: (a) medicinal or veterinary products as defined by Directive 2001/82/EC and Directive 2001/83/EC; (b) cosmetic products as defined by Directive 76/768/EEC; (c) the following fuels and oil products: motor fuels which are covered by Directive 98/70/EC, mineral oil products intended for use as fuel in mobile or fixed combustion plants, fuels sold in closed systems (e.g. liquid gas bottles); (d) artists’ paints covered by Directive 1999/45/EC; (e) the substances listed in Appendix 11, column 1, for the applications or uses listed in Appendix 11, column 2. Where a date is specified in column 2 of Appendix 11, the derogation shall apply until the said date. | |
| Entry 40 | Before | 40. Substances classified as flammable gases category 1 or 2, flammable liquids categories 1, 2 or 3, flammable solids category 1 or 2, substances and mixtures which, in contact with water, emit flammable gases, category 1, 2 or 3, pyrophoric liquids category 1 or pyrophoric solids category 1, regardless of whether they appear in Part 3 of Annex VI to | 1. Shall not be used, as substance or as mixtures in aerosol dispensers where these aerosol dispensers are intended for supply to the general public for entertainment and decorative purposes such as the following: metallic glitter intended mainly for decoration, artificial snow and frost, whoopee cushions, silly string aerosols, imitation excrement, horns for parties, decorative flakes and foams, artificial cobwebs, stink bombs. 2. Without prejudice to the application of other Community provisions on the classification, packaging and labelling of substances, suppliers shall ensure before the placing on the market that the packaging of aerosol dispensers referred to above is marked visibly, legibly and indelibly with: For professional users only. 3. By way of derogation, paragraphs 1 and 2 shall not apply to the aerosol dispensers referred to Article 8 (1a) of Council Directive 75/324/EEC . 4. The aerosol dispensers referred to in paragraphs 1 and 2 shall not be placed on the market unless they conform to the requirements indicated. |
| After | 40. Substances classified as flammable gases category 1 or 2, flammable liquids categories 1, 2 or 3, flammable solids category 1 or 2, substances and mixtures which, in contact with water, emit flammable gases, category 1, 2 or 3, pyrophoric liquids category 1 or pyrophoric solids category 1, regardless of whether they appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 or not. | 1. Shall not be used, as substance or as mixtures in aerosol dispensers where these aerosol dispensers are intended for supply to the general public for entertainment and decorative purposes such as the following: metallic glitter intended mainly for decoration, artificial snow and frost, whoopee cushions, silly string aerosols, imitation excrement, horns for parties, decorative flakes and foams, artificial cobwebs, stink bombs. 2. Without prejudice to the application of other Community provisions on the classification, packaging and labelling of substances, suppliers shall ensure before the placing on the market that the packaging of aerosol dispensers referred to above is marked visibly, legibly and indelibly with: For professional users only. 3. By way of derogation, paragraphs 1 and 2 shall not apply to the aerosol dispensers referred to Article 8 (1a) of Council Directive 75/324/EEC . 4. The aerosol dispensers referred to in paragraphs 1 and 2 shall not be placed on the market unless they conform to the requirements indicated. | |
| Entry 47 | Before | 47. Chromium VI compounds | 1. Cement and cement-containing mixtures shall not be placed on the market, or used, if they contain, when hydrated, more than 2 mg/kg (0,0002 %) soluble chromium VI of the total dry weight of the cement. 2. If reducing agents are used, then without prejudice to the application of other Community provisions on the classification, packaging and labelling of substances and mixtures, suppliers shall ensure before the placing on the market that the packaging of cement or cement-containing mixtures is visibly, legibly and indelibly marked with information on the packing date, as well as on the storage conditions and the storage period appropriate to maintaining the activity of the reducing agent and to keeping the content of soluble chromium VI below the limit indicated in paragraph 1. 3. By way of derogation, paragraphs 1 and 2 shall not apply to the placing on the market for, and use in, controlled closed and totally automated processes in which cement and cement-containing mixtures are handled solely by machines and in which there is no possibility of contact with the skin. |
| After | 47. Chromium VI compounds | 1. Cement and cement-containing mixtures shall not be placed on the market, or used, if they contain, when hydrated, more than 2 mg/kg (0,0002 %) soluble chromium VI of the total dry weight of the cement. 2. If reducing agents are used, then without prejudice to the application of other Community provisions on the classification, packaging and labelling of substances and mixtures, suppliers shall ensure before the placing on the market that the packaging of cement or cement-containing mixtures is visibly, legibly and indelibly marked with information on the packing date, as well as on the storage conditions and the storage period appropriate to maintaining the activity of the reducing agent and to keeping the content of soluble chromium VI below the limit indicated in paragraph 1. 3. By way of derogation, paragraphs 1 and 2 shall not apply to the placing on the market for, and use in, controlled closed and totally automated processes in which cement and cement-containing mixtures are handled solely by machines and in which there is no possibility of contact with the skin.4. The standard adopted by the European Committee for Standardization (CEN) for testing the water-soluble chromium (VI) content of cement and cement-containing mixtures shall be used as the test method for demonstrating conformity with paragraph 1. | |
| Entry 56CAS 101-68-8CAS 2536-05-2CAS 26447-40-5CAS 5873-54-1EC 202-966-0EC 219-799-4EC 227-534-9EC 247-714-0 | Before | 56. Methylenediphenyl diisocyanate (MDI) CAS No 26447-40-5 EC No 247-714-0 | 1. Shall not be placed on the market after 27 December 2010, as a constituent of mixtures in concentrations equal to or greater than 0,1 % by weight of MDI for supply to the general public, unless suppliers shall ensure before the placing on the market that the packaging: (a) contains protective gloves which comply with the requirements of Council Directive 89/686/EEC ; (b) is marked visibly, legibly and indelibly as follows, and without prejudice to other Community legislation concerning the classification, packaging and labelling of substances and mixtures: — Persons already sensitised to diisocyanates may develop allergic reactions when using this product. — Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. — This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used. 2. By way of derogation, paragraph 1(a) shall not apply to hot melt adhesives. |
| After | 56. Methylenediphenyl diisocyanate (MDI) CAS No 26447-40-5 EC No 247-714-0including the following specific isomers: (a) 4,4’-Methylenediphenyl diisocyanate: CAS No 101-68-8 EC No 202-966-0; (b) 2,4’-Methylenediphenyl diisocyanate: CAS No 5873-54-1 EC No 227-534-9; (c) 2,2’-Methylenediphenyl diisocyanate: CAS No 2536-05-2 EC No 219-799-4 | 1. Shall not be placed on the market after 27 December 2010, as a constituent of mixtures in concentrations equal to or greater than 0,1 % by weight of MDI for supply to the general public, unless suppliers shall ensure before the placing on the market that the packaging: (a) contains protective gloves which comply with the requirements of Council Directive 89/686/EEC ; (b) is marked visibly, legibly and indelibly as follows, and without prejudice to other Community legislation concerning the classification, packaging and labelling of substances and mixtures: — Persons already sensitised to diisocyanates may develop allergic reactions when using this product. — Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. — This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used. 2. By way of derogation, paragraph 1(a) shall not apply to hot melt adhesives. |
| Identifiers | Version | Substances | Index No | EC No | CAS No | Notes |
|---|---|---|---|---|---|---|
| Index No 607-426-00-1CAS 131-18-0CAS 42925-80-4CAS 84777-06-0EC 205-017-9EC 284-032-2 | Before | 1,2-benzenedicarboxylic acid, dipentylester, branched and linear [1]
| 607-426-00-1 | 284-032-2 | 84777-06-0 | |
| After | 1,2-benzenedicarboxylic acid, dipentylester, branched and linear [1] | 607-426-00-1 | 284-032-2 [1] | 84777-06-0 [1] |
1 entry differs only in spacing, dash forms or accents
| Identifiers | Version | Substances | Index No | EC No | CAS No | Notes |
|---|---|---|---|---|---|---|
| Index No 649-093-00-5CAS 68606-25-7EC 271-734-9 | Before | Hydrocarbons, C2-4; Petroleum gas | 649-093-00-5 | 271-734-9 | 68606-25-7 | |
| After | Hydrocarbons, C2-4; Petroleum gas | 649-093-00-5 | 271-734-9 | 68606-25-7 | H,K |
Text from EUR-Lex, before and after
Previous version, in force 9 October 2012 02006R1907-20121009 → this version, in force 6 March 2013 02006R1907-20130306
compared line by line: this provision is too large to compare word by word, so a marked line is a line that changed somewhere
ANNEX XVII
RESTRICTIONS ON THE MANUFACTURE, PLACING ON THE MARKET AND USE OF CERTAIN DANGEROUS SUBSTANCES, MIXTURES AND ARTICLES
For substances which have been incorporated in this Annex as a consequence of restrictions adopted in the framework of Directive 76/769/EEC (Entries 1 to 58), the restrictions shall not apply to storage, keeping, treatment, filling into containers, or transfer from one container to another of these substances for export, unless the manufacture of the substances is prohibited.
… 66 unchanged lines …
CAS No 77536-68-6
(f) Chrysotile
CAS No 12001-29-5
CAS No 132207-32-0 1. The manufacture, placing on the market and use of these fibres and of articles containing these fibres added intentionally is prohibited. CAS No 132207-32-0 1. The manufacture, placing on the market and use of these fibres and of articles and mixtures containing these fibres added intentionally is prohibited.
However, Member States may exempt the placing on the market and use of diaphragms containing chrysotile (point (f)) for existing electrolysis installations until they reach the end of their service life, or until suitable asbestos-free substitutes become available, whichever is the sooner.
By 1 June 2011 Member States making use of this exemption shall provide a report to the Commission on the availability of asbestos free substitutes for electrolysis installations and the efforts undertaken to develop such alternatives, on the protection of the health of workers in the installations, on the source and quantities of chrysotile, on the source and quantities of diaphragms containing chrysotile, and the envisaged date of the end of the exemption. The Commission shall make this information publicly available.
Following receipt of those reports, the Commission shall request the Agency to prepare a dossier in accordance with Article 69 with a view to prohibit the placing on the market and use of diaphragms containing chrysotile.
… 67 unchanged lines …
(b) Trilead-bis(carbonate)-dihydroxide 2Pb CO3-Pb(OH)2
CAS No 1319-46-6
EC No 215-290-6 Shall not be placed on the market, or used, as substances or in mixtures, where the substance or mixture is intended for use as paint.
However, Member States may, in accordance with the provisions of International Labour Organisation (ILO) Convention 13 on the use of white lead and sulphates of lead in paint, permit the use on their territory of the substance or mixture for the restoration and maintenance of works of art and historic buildings and their interiors. However, Member States may, in accordance with the provisions of International Labour Organization (ILO) Convention 13, permit the use on their territory of the substance or mixture for the restoration and maintenance of works of art and historic buildings and their interiors, as well as the placing on the market for such use. Where a Member State makes use of this derogation, it shall inform the Commission thereof.
17. Lead sulphates:
(a) PbSO4
CAS No 7446-14-2
EC No 231-198-9
(b) Pbx SO4
CAS No 15739-80-7
EC No 239-831-0 Shall not be placed on the market, or used, as substances or in mixtures, where the substance or mixture is intended for use as paint.
However, Member States may, in accordance with the provisions of ILO Convention 13 on the use of white lead and sulphates of lead in paint, permit the use on their territory of the substance or mixture for the restoration and maintenance of works of art and historic buildings and their interiors. However, Member States may, in accordance with the provisions of International Labour Organization (ILO) Convention 13, permit the use on their territory of the substance or mixture for the restoration and maintenance of works of art and historic buildings and their interiors, as well as the placing on the market for such use. Where a Member State makes use of this derogation, it shall inform the Commission thereof.
18. Mercury compounds Shall not be placed on the market, or used, as substances or in mixtures where the substance or mixture is intended for use:
(a) to prevent the fouling by micro-organisms, plants or animals of:
the hulls of boats,
… 204 unchanged lines …
in mixtures,
for supply to the general public when the individual concentration in the substance or mixture is equal to or greater than:
either the relevant specific concentration limit specified in Part 3 of Annex VI to Regulation (EC) No 1272/2008, or,
the relevant concentration specified in Directive 1999/45/EC. the relevant concentration specified in Directive 1999/45/EC where no specific concentration limit is set out in Part 3 of Annex VI to Regulation (EC) No 1272/2008.
Without prejudice to the implementation of other Community provisions relating to the classification, packaging and labelling of substances and mixtures, suppliers shall ensure before the placing on the market that the packaging of such substances and mixtures is marked visibly, legibly and indelibly as follows:
Restricted to professional users.
2. By way of derogation, paragraph 1 shall not apply to:
… 79 unchanged lines …
By way of derogation this provision shall not apply to:
(a) medicinal or veterinary products as defined by Directive 2001/82/EC and Directive 2001/83/EC;
(b) cosmetic products as defined by Directive 76/768/EEC.
40. Substances classified as flammable gases category 1 or 2, flammable liquids categories 1, 2 or 3, flammable solids category 1 or 2, substances and mixtures which, in contact with water, emit flammable gases, category 1, 2 or 3, pyrophoric liquids category 1 or pyrophoric solids category 1, regardless of whether they appear in Part 3 of Annex VI to that Regulation or not. 1. Shall not be used, as substance or as mixtures in aerosol dispensers where these aerosol dispensers are intended for supply to the general public for entertainment and decorative purposes such as the following: 40. Substances classified as flammable gases category 1 or 2, flammable liquids categories 1, 2 or 3, flammable solids category 1 or 2, substances and mixtures which, in contact with water, emit flammable gases, category 1, 2 or 3, pyrophoric liquids category 1 or pyrophoric solids category 1, regardless of whether they appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 or not. 1. Shall not be used, as substance or as mixtures in aerosol dispensers where these aerosol dispensers are intended for supply to the general public for entertainment and decorative purposes such as the following:
metallic glitter intended mainly for decoration,
artificial snow and frost,
whoopee cushions,
… 64 unchanged lines …
47. Chromium VI compounds 1. Cement and cement-containing mixtures shall not be placed on the market, or used, if they contain, when hydrated, more than 2 mg/kg (0,0002 %) soluble chromium VI of the total dry weight of the cement.
2. If reducing agents are used, then without prejudice to the application of other Community provisions on the classification, packaging and labelling of substances and mixtures, suppliers shall ensure before the placing on the market that the packaging of cement or cement-containing mixtures is visibly, legibly and indelibly marked with information on the packing date, as well as on the storage conditions and the storage period appropriate to maintaining the activity of the reducing agent and to keeping the content of soluble chromium VI below the limit indicated in paragraph 1.
3. By way of derogation, paragraphs 1 and 2 shall not apply to the placing on the market for, and use in, controlled closed and totally automated processes in which cement and cement-containing mixtures are handled solely by machines and in which there is no possibility of contact with the skin.
4. The standard adopted by the European Committee for Standardization (CEN) for testing the water-soluble chromium (VI) content of cement and cement-containing mixtures shall be used as the test method for demonstrating conformity with paragraph 1.
48. Toluene
CAS No 108-88-3
EC No 203-625-9 Shall not be placed on the market, or used, as a substance or in mixtures in a concentration equal to or greater than 0,1 % by weight where the substance or mixture is used in adhesives or spray paints intended for supply to the general public.
… 88 unchanged lines …
Do not use in paint spraying equipment.
56. Methylenediphenyl diisocyanate (MDI)
CAS No 26447-40-5
EC No 247-714-0 1. Shall not be placed on the market after 27 December 2010, as a constituent of mixtures in concentrations equal to or greater than 0,1 % by weight of MDI for supply to the general public, unless suppliers shall ensure before the placing on the market that the packaging: EC No 247-714-0
including the following specific isomers:
(a) 4,4’-Methylenediphenyl diisocyanate:
CAS No 101-68-8
EC No 202-966-0;
(b) 2,4’-Methylenediphenyl diisocyanate:
CAS No 5873-54-1
EC No 227-534-9;
(c) 2,2’-Methylenediphenyl diisocyanate:
CAS No 2536-05-2
EC No 219-799-4 1. Shall not be placed on the market after 27 December 2010, as a constituent of mixtures in concentrations equal to or greater than 0,1 % by weight of MDI for supply to the general public, unless suppliers shall ensure before the placing on the market that the packaging:
(a) contains protective gloves which comply with the requirements of Council Directive 89/686/EEC
;
(b) is marked visibly, legibly and indelibly as follows, and without prejudice to other Community legislation concerning the classification, packaging and labelling of substances and mixtures:
… 2,141 unchanged lines …
Hydrocarbons, C1-4, debutaniser fraction; Petroleum gas 649-091-00-4 271-261-8 68527-19-5 H, K
Gases (petroleum), C1-5, wet; Petroleum gas
(A complex combination of hydrocarbons produced by the distillation of crude oil and/or the cracking of tower gas oil. It consists of hydrocarbons having carbon numbers predominantly in the range of C1 through C5.) 649-092-00-X 271-624-0 68602-83-5 H, K
Hydrocarbons, C2-4; Petroleum gas 649-093-00-5 271-734-9 68606-25-7 H, K Hydrocarbons, C2-4; Petroleum gas 649-093-00-5 271-734-9 68606-25-7 H,K
Hydrocarbons, C3; Petroleum gas 649-094-00-0 271-735-4 68606-26-8 H, K
Gases (petroleum), alkylation feed; Petroleum gas
(A complex combination of hydrocarbons produced by the catalytic cracking of gas oil. It consists of hydrocarbons having carbon numbers predominantly in the range of C3 through C4.) 649-095-00-6 271-737-5 68606-27-9 H, K
… 52 unchanged lines …
Gases (petroleum), blend oil, hydrogen-nitrogen-rich; Refinery gas
(A complex combination of hydrocarbons obtained by distillation of a blend oil. It consists primarily of hydrogen and nitrogen with various small amounts of carbon monoxide, carbon dioxide, and aliphatic hydrocarbons having carbon numbers predominantly in the range of C1 through C5.) 649-123-00-7 270-749-8 68477-68-9 H, K
Gases (petroleum), catalytic reformed naphtha stripper overheads; Refinery gas
(A complex combination of hydrocarbons obtained from stabilisation of catalytic reformed naphtha. It consists of hydrogen and saturated hydrocarbons having carbon numbers predominantly in the range of C1 through C4.) 649-124-00-2 270-759-2 68477-77-0 H, K (A complex combination of hydrocarbons obtained from stabilisation of catalytic reformed naphtha. It consists of hydrogen and saturated hydrocarbons having carbon numbers predominantly in the range of C1 through C4.) 649-124-00-2 270-759-2 68477-77-0 H, K
Gases (petroleum), C6-8 catalytic reformer recycle; Refinery gas
(A complex combination of hydrocarbons produced by distillation of products from catalytic reforming of C6-C8 feed and recycled to conserve hydrogen. It consists primarily of hydrogen. It may also contain various small amounts of carbon monoxide, carbon dioxide, nitrogen, and hydrocarbons having carbon numbers predominantly in the range of C1 through C6.) 649-125-00-8 270-761-3 68477-80-5 H, K
Gases (petroleum), C6-8 catalytic reformer; Refinery gas
… 677 unchanged lines …
(AEEA) 603-194-00-0 203-867-5 111-41-1 1,2-Diethoxyethane 603-208-00-5 211-076-1 629-14-1 4,4'-isobutylethylidenediphenol; 2,2-bis (4'-hydroxyphenyl)-4-methylpentane 604-024-00-8 401-720-1 6807-17-6 (E)-3-[1-[4-[2-(dimethylamino)ethoxy]phenyl]-2-phenylbut-1-enyl]phenol 604-073-00-5 428-010-4 82413-20-5 N-methyl-2-pyrrolidone;
1-Methyl-2-pyrrolidone 606-021-00-7 212-828-1 872-50-4 Tetrahydrothiopyran-3-carboxaldehyde 606-062-00-0 407-330-8 61571-06-0 2-Butyryl-3-hydroxy-5-thiocyclohexan-3-yl-cyclohex-2-en-1-one 606-100-00-6 425-150-8 94723-86-1 Cyclic 3-(1,2-ethanediylacetale)-estra-5(10),9(11)-diene-3,17-dione 606-131-00-5 427-230-8 5571-36-8 2-Methoxyethyl acetate; ethylene glycol monomethyl ether acetate; methylglycol acetate 607-036-00-1 203-772-9 110-49-6 2-Ethoxyethyl acetate; ethylene glycol monoethyl ether acetate; ethylglycol acetate 607-037-00-7 203-839-2 111-15-9 2-Ethylhexyl 3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl methyl thio acetate 607-203-00-9 279-452-8 80387-97-9 Bis(2-Methoxyethyl) phthalate 607-228-00-5 204-212-6 117-82-8 2-Methoxypropyl acetate 607-251-00-0 274-724-2 70657-70-4 Fluazifop-butyl (ISO); butyl (RS)-2-[4-(5-trifluoromethyl-2-pyridyloxy)phenoxy]propionate 607-304-00-8 274-125-6 69806-50-4 Vinclozolin (ISO); N-3,5-Dichlorophenyl-5-methyl-5-vinyl-1,3-oxazolidine-2,4-dione 607-307-00-4 256-599-6 50471-44-8 Methoxyacetic acid 607-312-00-1 210-894-6 625-45-6 E
Bis(2-ethylhexyl) phthalate; di-(2-ethylhexyl) phthalate; DEHP 607-317-00-9 204-211-0 117-81-7 Dibutyl phthalate; DBP 607-318-00-4 201-557-4 84-74-2 (+/-) tetrahydrofurfuryl (R)-2-[4-(6-chloroquinoxalin-2-yloxy)phenyloxy]propionate 607-373-00-4 414-200-4 119738-06-6 E
1,2-benzenedicarboxylic acid, dipentylester, branched and linear [1]
n-pentyl-isopentylphthalate [2]
di-n-pentyl phthalate [3]
Diisopentylphthalate [4] 607-426-00-1 284-032-2 [1]-[2]
205-017-9 [3]-[4] 84777-06-0 [1]-[2]
131-18-0 [3]
42925-80-4 [4] Benzyl butyl phthalate 1,2-benzenedicarboxylic acid, dipentylester, branched and linear [1] 607-426-00-1 284-032-2 [1] 84777-06-0 [1] n-pentyl-isopentylphthalate [2] [2] [2] di-n-pentyl phthalate [3] 205-017-9 [3] 131-18-0 [3] Diisopentylphthalate [4] 210-088-4 [4] 605-50-5 [4] Benzyl butyl phthalate
BBP 607-430-00-3 201-622-7 85-68-7 1,2-Benzenedicarboxylic acid
di-C7-11-branched and linear alkylesters 607-480-00-6 271-084-6 68515-42-4 1,2-Benzenedicarboxylic acid;
Di-C6-8-branched alkylesters, C7-rich 607-483-00-2 276-158-1 71888-89-6 A mixture of: disodium 4-(3-ethoxycarbonyl-4-(5-(3-ethoxycarbonyl-5-hydroxy-1-(4-sulfonatophenyl)pyrazol-4-yl)penta-2,4-dienylidene)-4,5-dihydro-5-oxopyrazol-1-yl)benzenesulfonate;
… 106 unchanged lines …
Appendix 10
Entry 43 — Azocolourants — List of testing methods
List of testing methods
ESO: European standardisation organisations:
CEN: Avenue Marnix 17, 1000 Brussels, Belgium, tel. +32 2550 08 11, fax +32 2550 08 19 (http://www.cen.eu/cenorm/homepage.htm)
Cenelec: Avenue Marnix 17, B-1000 Brussels, tel. +32 25196871, fax +32 2519 69 19 (http://www.cenelec.eu/Cenelec/Homepage.htm)
ETSI: 650, route des Lucioles, F-06921 Sophia Antipolis; tel. (33) 492 94 42 00, fax (33) 493 65 47 16. http://www.etsi.org
European standardisation organisation
Reference and title of the standard Reference document Reference of the superseded standard
CEN Leather — Chemical tests — Determination of certain azocolorants in dyed leathers CEN ISO/TS 17234:2003 NONE
CEN Textiles — Methods for the determination of certain aromatic amines derived from azocolorants — Part 1: Detection of the use of certain azo colorants accessible without extraction EN 14362-1:2003 NONE
CEN Textiles — Methods for determination of certain aromatic amines derived from azocolorants — Part 2: Detection of the use of certain azo colorants accessible by extracting the fibres EN 14362-2:2003 NONE
Appendix 11 European standardisation organisation Reference and title of the harmonised standard Reference of the superseded standard
CEN EN ISO 17234-1:2010
Leather — Chemical tests for the determination of certain azo colorants in dyed leathers — Part 1: Determination of certain aromatic amines derived from azo colorants CEN ISO/TS 17234:2003
CEN EN ISO 17234-2:2011
Leather — Chemical tests for the determination of certain azo colorants in dyed leathers — Part 2: Determination of 4-aminoazobenzene CEN ISO/TS 17234:2003
CEN EN 14362-1:2012
Textiles — Methods for determination of certain aromatic amines derived from azo colorants — Part 1: Detection of the use of certain azo colorants accessible with and without extracting the fibres EN 14362-1:2003
EN 14362-2:2003
CEN EN 14362-3:2012
Textiles — Methods for determination of certain aromatic amines derived from azo colorants — Part 3: Detection of the use of certain azo colorants, which may release 4-aminoazobenzene Appendix 11
Entries 28 to 30 — Derogations for specific substances
OJ L 104, 8.4.2004, p. 1.
Substances Derogations
1. (a) Sodium perborate; perboric acid, sodium salt; perboric acid, sodium salt, monohydrate; sodium peroxometaborate; perboric acid (HBO(O2)), sodium salt, monohydrate; sodium peroxoborate
CAS No 15120-21-5; 11138-47-9; 12040-72-1; 7632-04-4; 10332-33-9
EC No 239-172-9; 234-390-0; 231-556-4
(b) Perboric acid (H3BO2(O2)), monosodium salt trihydrate; perboric acid, sodium salt, tetrahydrate; perboric acid (HBO(O2)), sodium salt, tetrahydrate; sodium peroxoborate hexahydrate
CAS No 13517-20-9; 37244-98-7; 10486-00-7
EC No 239-172-9; 234-390-0; 231-556-4 Detergents as defined by Regulation (EC) No 648/2004 of the European Parliament and of the Council
. The derogation shall apply until 1 June 2013.
The full entry is committed at eu/32006R1907/CHANGELOG.md.