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Provision history · Plant Protection Products Regulation

Annex III

Plant Protection Products Regulation · 32009R1107 · every version of this act · on EUR-Lex (external, EUR-Lex)

2 changes recorded across 2 versions, newest first.

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Version in force , Modified +1,647 −0

Amended by Regulation (EU) 2026/1120 32026R1120 on EUR-Lex (external, EUR-Lex)

Applies from: no date changed

Explanation, written by a model and checked against the cited text

The AFTER text adds twelve new numbered entries (145 through 156) to the table of co-formulants not accepted for inclusion in plant protection products, listing substances such as acetaldehyde, propylene oxide, cumene, several cyclosiloxanes, bumetrizole, a further petroleum distillate, a quaternary ammonium chloride compound, a perfluoroalkyl phosphinic acid derivative, 1,4-dioxane and a propionaldehyde derivative, each with its associated names, CAS/EC numbers and classification or property.

All 144 entries present in the BEFORE version remain unchanged in content and order in the AFTER version.

Cited: Annex III, v2 (external, EUR-Lex) · Annex III, v1 (external, EUR-Lex)

v1 is the previous version, v2 this one.

12 entries added, 0 amended, 0 removed.

12 entries added

Added entries, Annex III, table 1
IdentifiersNoNameEC names/Other namesCAS numberEC numberClassification/Other properties
No 145CAS 75-07-0EC 200-836-8145.AcetaldehydeEthanal75-07-0200-836-8Carcinogenic cat. 1B
No 146CAS 75-56-9EC 200-879-2146.Propylene oxide1,2-epoxypropane; methyloxirane75-56-9200-879-2Carcinogenic cat. 1B/ Mutagenic cat. 1B
No 147CAS 98-82-8EC 202-704-5147.Cumene(1-Methylethyl)benzene98-82-8202-704-5Carcinogenic cat. 1B
No 148CAS 540-97-6EC 208-762-8148.Dodecamethylcyclohexasiloxane; (D6)540-97-6208-762-8Persistent, bioaccumulative and toxic (REACH Article 57(d); Very persistent and very bioaccumulative (REACH Article 57(e)
No 149CAS 541-02-6EC 208-764-9149.Decamethylcyclopentasiloxane; (D5)541-02-6208-764-9Persistent, bioaccumulative and toxic (REACH Article 57(d); Very persistent and very bioaccumulative (REACH Article 57(e)
No 150CAS 556-67-2EC 209-136-7150.Octamethylcyclotetrasiloxane; (D4)556-67-2209-136-7Persistent, bioaccumulative and toxic (REACH Article 57(d); Very persistent and very bioaccumulative (REACH Article 57(e)
No 151CAS 3896-11-5EC 223-445-4151.2-(2'-hydroxy-3'-tert-butyl-5'-methylphenyl)-5-chlorobenzotriazoleBumetrizole3896-11-5223-445-4Very persistent and very bioaccumulative (REACH Article 57(e)
No 152CAS 64742-56-9EC 265-159-2152.Distillates (petroleum) solvent-dewaxed light paraffinic with a content of ≥ 3,0 % DMSO-extract (measured by IP 346)64742-56-9265-159-2Carcinogenic cat. 1B
No 153CAS 4080-31-3EC 223-805-0153.3,5,7-Triaza-1-azoniatricyclo[3.3.1.1 3,7] decane,1-(3-chloro-2-propen-1-yl)-, chlorideMethenamine 3-chloroallylochloride (CTAC)4080-31-3223-805-0Not approved for use in biocidal products for product-type 6 (preservatives for products during storage)
No 154CAS 68412-69-1EC 270-206-5154.Phosphinic acid, bis(perfluoro-C6-12-alkyl) derivatives68412-69-1270-206-5Persistent organic pollutant (POP)
No 155CAS 123-91-1EC 204-661-8155.1,4-dioxane123-91-1204-661-8Carcinogenic cat. 1B
No 156CAS 80-54-6EC 201-289-8156.2-(4-tert-butylbenzyl)propionaldehyde80-54-6201-289-8Toxic to reproduction cat.1B
Text from EUR-Lex, before and after

Previous version, in force 21 November 2022 02009R1107-20221121 → this version, in force 16 June 2026 02009R1107-20260616

ANNEX III List of co-formulants which are not accepted for inclusion in plant protection products as referred to in Article 27 The limit for the acceptable presence of the substances listed in the table as unintentional impurity in the finished product is … 2,028 unchanged words … 201-173-7 Carcinogenic cat.1B/ Mutagenic cat.1B 142. Pyridine, alkyl derivatives, with a content of ≥ 0,1 % benzene (EC No 200-753-7) 68391-11-7 269-929-9 Carcinogenic cat.1A/ Mutagenic cat.1B 143. Quinoline Quinoline 91-22-5 202-051-6 Carcinogenic cat.1B 144. Tetrahydrofurfuryl Alcohol Tetrahydrofurfuryl alcohol; 2-Furanmethanol, tetrahydro- 97-99-4 202-625-6 Toxic to reproduction cat.1B145. Acetaldehyde Ethanal 75-07-0 200-836-8 Carcinogenic cat. 1B 146. Propylene oxide 1,2-epoxypropane; methyloxirane 75-56-9 200-879-2 Carcinogenic cat. 1B/ Mutagenic cat. 1B 147. Cumene (1-Methylethyl)benzene 98-82-8 202-704-5 Carcinogenic cat. 1B 148. Dodecamethylcyclohexasiloxane; (D6) 540-97-6 208-762-8 Persistent, bioaccumulative and toxic (REACH Article 57(d); Very persistent and very bioaccumulative (REACH Article 57(e) 149. Decamethylcyclopentasiloxane; (D5) 541-02-6 208-764-9 Persistent, bioaccumulative and toxic (REACH Article 57(d); Very persistent and very bioaccumulative (REACH Article 57(e) 150. Octamethylcyclotetrasiloxane; (D4) 556-67-2 209-136-7 Persistent, bioaccumulative and toxic (REACH Article 57(d); Very persistent and very bioaccumulative (REACH Article 57(e) 151. 2-(2'-hydroxy-3'-tert-butyl-5'-methylphenyl)-5-chlorobenzotriazole Bumetrizole 3896-11-5 223-445-4 Very persistent and very bioaccumulative (REACH Article 57(e) 152. Distillates (petroleum) solvent-dewaxed light paraffinic with a content of ≥ 3,0 % DMSO-extract (measured by IP 346) 64742-56-9 265-159-2 Carcinogenic cat. 1B 153. 3,5,7-Triaza-1-azoniatricyclo[3.3.1.1 3,7] decane,1-(3-chloro-2-propen-1-yl)-, chloride Methenamine 3-chloroallylochloride (CTAC) 4080-31-3 223-805-0 Not approved for use in biocidal products for product-type 6 (preservatives for products during storage) 154. Phosphinic acid, bis(perfluoro-C6-12-alkyl) derivatives 68412-69-1 270-206-5 Persistent organic pollutant (POP) 155. 1,4-dioxane 123-91-1 204-661-8 Carcinogenic cat. 1B 156. 2-(4-tert-butylbenzyl)propionaldehyde 80-54-6 201-289-8 Toxic to reproduction cat.1B

Version in force , Modified

Amended by Regulation (EU) 2019/1381 32019R1381 on EUR-Lex (external, EUR-Lex) · Regulation (EU) 2021/383 32021R0383 on EUR-Lex (external, EUR-Lex)

Applies from: not readable (the text changed beyond its dates, so no date that moved can be read as the application date) why

dates added to the text: 1818-08-02

Explanation, written by a model and checked against the cited text

The later version adds introductory impurity-limit statements and a full table of substances with names, CAS and EC numbers and classification or other properties, none of which appeared in the earlier version, which contained only the heading and the introductory sentence about Article 27.

The added table lists numbered entries covering a wide range of chemical substances, including entries such as phenol, 4-(1-methylheptyl)- with CAS number 1818-08-2, each paired with classification or property information such as carcinogenic, mutagenic, toxic to reproduction, or endocrine disrupting properties.

The limit for the acceptable presence of the substances listed in the table as unintentional impurity in the finished product is 0,1 % (weight by weight (w/w)) except where stated otherwise in this Annex.

Cited: Annex III, v1 (external, EUR-Lex) · Annex III, v2 (external, EUR-Lex)

v1 is the previous version, v2 this one.

Text from EUR-Lex, on this version's page