Version · CLP
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Made by Regulation (EU) 2024/2564 32024R2564 on EUR-Lex (external, EUR-Lex)
Version 29 of 31 recorded for CLP.
First seen by emendrix on , when it first read this version; that is not a legal date.
2 changes in this version
Consolidated versions 02008R1272-20250901 → 02008R1272-20260501. v1 is the previous version, v2 this one.
What changed
Annex VI Harmonised classification and labelling for certain hazardous substances, Modified§
Not in every listWhat this means
Found in the text, but not every source lists it — the text comparison found this change; the EU's own amendment metadata does not list it. The source that does not name it is the EU's own amendment metadata. Both are shown; neither is overruled.
Explanation, written by a model and checked against the cited text
The entry for trimethyl borate (index 005-005-00-1) has been changed so that, in addition to the flammable liquid classification, it now carries a Repr. 1B classification with hazard statement H360FD, alongside a revised Acute Tox. 4 entry, and its pictograms, labelling codes and hazard statements have been updated accordingly, with a Note 11 reference added.
In the earlier version this same entry showed only the flammable liquid and Acute Tox. 4 classifications with hazard statements H226 and H312, without any reproductive toxicity classification or Note 11 reference.
The remainder of the visible Annex VI text, including the introductory parts and the surrounding table entries, is unchanged between the two versions, and the material beyond the truncation marker in both texts is not part of what can be described here.
Cited: Annex VI, v2 (external, EUR-Lex) · Annex VI, v1 (external, EUR-Lex)
v1 is the previous version, v2 this one.
Each CAS and EC number in these tables links to its own page, which lists every entry that prints it across the acts this record holds.
25 entries added, 14 amended, 0 removed.
1 row carries no key and is not compared.
25 entries added
| Identifiers | Index No | Chemical name | EC No | CAS No | Classification | Labelling | Specific Conc. Limits, M-factors and ATEs | Notes | |||
|---|---|---|---|---|---|---|---|---|---|---|---|
| Hazard Class and Category Code(s) | Hazard statement Code(s) | Pictogram, Signal Word Code(s) | Hazard statement Code(s) | Suppl. Hazard statement Code(s) | |||||||
| Index No 005-023-00-XCAS 10486-00-7CAS 13517-20-9CAS 37244-98-7EC 234-390-0EC 239-172-9 | 005-023-00-X | perboric acid (H3BO2(O2)), monosodium salt trihydrate [1] perboric acid, sodium salt, tetrahydrate [2] perboric acid (HBO(O2)), sodium salt, tetrahydrate [3] sodium peroxoborate, hexahydrate [4] | 239-172-9 [1] 234-390-0 [2] - [3] - [4] | 13517-20-9 [1] 37244-98-7 [2] 10486-00-7 [3] - [4] | Repr. 1B Acute Tox. 4 STOT SE 3 Eye Dam. 1 | H360FD H332 H335 H318 | GHS08 GHS05 GHS07 Dgr | H360FD H332 H335 H318 | inhalation: ATE = 1,2 mg/L (dusts or mists) Eye Dam. 1; H318: C ≥ 36 % Eye Irrit. 2; H319: 22 % ≤ C < 36 % | 11 | |
| Index No 005-024-00-5CAS 7632-04-4EC 231-556-4 | 005-024-00-5 | sodium peroxometaborate | 231-556-4 | 7632-04-4 | Ox. Sol. 2 Repr. 1B Acute Tox. 3 Acute Tox. 4 STOT SE 3 Eye Dam. 1 | H272 H360FD H331 H302 H335 H318 | GHS03 GHS08 GHS06 GHS05 Dgr | H272 H360FD H331 H302 H335 H318 | inhalation: ATE = 0,62 mg/L (dusts or mists) oral: ATE = 730 mg/kg bw Eye Dam. 1; H318: C ≥ 22 % Eye Irrit. 2; H319: 14 % ≤ C < 22 % | 11 | |
| Index No 006-104-00-2 | 006-104-00-2 | multi-walled carbon tubes (synthetic graphite in tubular shape) with a geometric tube diameter range ≥ 30 nm to < 3 μm and a length ≥ 5 μm and aspect ratio > 3:1, including multi-walled carbon nanotubes, MWC(N)T | — | — | Carc. 1B STOT RE 1 | H350i H372 (lung)(inhalation) | GHS08 Dgr | H350i H372 (lung)(inhalation) | STOT RE 1; H372: C ≥ 1 %; STOT RE 2; H373: 0,1 % ≤ C < 1 % | ||
| Index No 029-026-00-0CAS 7440-50-8EC 231-159-6 | 029-026-00-0 | copper [specific surface area > 0,67 mm2/mg] | 231-159-6 | 7440-50-8 | Aquatic Acute 1 Aquatic Chronic 1 | H400 H410 | GHS09 Wng | H410 | M = 10 M = 1 | ||
| Index No 047-004-00-9CAS 7440-22-4EC 231-131-3 | 047-004-00-9 | silver massive: [particle diameter ≥ 1 mm] | 231-131-3 | 7440-22-4 | Repr. 2 STOT RE 2 | H361f H373 (nervous system) | GHS08 Wng | H361f H373 (nervous system) | |||
| Index No 047-005-00-4CAS 7440-22-4EC 231-131-3 | 047-005-00-4 | silver powder: [particle diameter > 100 nm < 1 mm] | 231-131-3 | 7440-22-4 | Repr. 2 STOT RE 2 Aquatic Acute 1 Aquatic Chronic 1 | H361f H373 (nervous system) H400 H410 | GHS08 GHS09 Wng | H361f H373 (nervous system) H410 | M = 10 M = 10 | ||
| Index No 047-006-00-XCAS 7440-22-4EC 231-131-3 | 047-006-00-X | silver nano: [particle diameter > 1 nm ≤ 100 nm] | 231-131-3 | 7440-22-4 | Repr. 2 STOT RE 2 Aquatic Acute 1 Aquatic Chronic 1 | H361f H373 (nervous system) H400 H410 | GHS08 GHS09 Wng | H361f H373 (nervous system) H410 | M = 1000 M = 1000 | ||
| Index No 603-247-00-8 | 603-247-00-8 | reaction mass of 1,3-dioxan-5-ol and 1,3-dioxolan-4-ylmethanol | — | — | Repr. 1B | H360Df | GHS08 Dgr | H360Df | |||
| Index No 605-042-00-9CAS 1205-17-0CAS 737776-59-9CAS 737776-68-0EC 214-881-6 | 605-042-00-9 | α-methyl-1,3-benzodioxole-5-propionaldehyde [1] (S)-α-methyl-1,3-benzodioxole-5-propionaldehyde; (2S)-3-(1,3-benzodioxol-5-yl)-2-methylpropanal [2] (R)-α-methyl-1,3-benzodioxole-5-propionaldehyde; (2R)-3-(1,3-benzodioxol-5-yl)-2-methylpropanal [3] | 214-881-6 [1] - [2] - [3] | 1205-17-0 [1] 737776-68-0 [2] 737776-59-9 [3] | Skin Sens. 1B | H317 | GHS07 Wng | H317 | |||
| Index No 605-043-00-4CAS 1335-66-6CAS 1423-46-7CAS 1726-47-2CAS 27939-60-2CAS 35145-02-9CAS 36635-35-5CAS 40702-26-9CAS 6754-27-4CAS 67634-07-5CAS 67801-65-4CAS 68039-48-5CAS 68039-49-6CAS 68737-61-1CAS 6975-94-6CAS 71832-78-5EC 215-638-7EC 215-833-7EC 248-742-6EC 252-395-6EC 253-139-6EC 266-810-3EC 267-186-5EC 268-263-6EC 268-264-1EC 272-113-5EC 276-055-1 | 605-043-00-4 | 2,4-dimethylcyclohex-3-ene-1-carbaldehyde [1] (1α,2α,5α)-2,5-dimethylcyclohex-3-ene-1-carbaldehyde [2] 2,6-dimethylcyclohex-3-ene-1-carbaldehyde [3] 3,5-dimethylcyclohex-3-ene-1-carbaldehyde [4] 3,6-dimethylcyclohex-3-ene-1-carbaldehyde [5] 4,6-dimethylcyclohex-3-ene-1-carbaldehyde [6] reaction mass of 3,5-dimethylcyclohex-3-ene-1-carbaldehyde and 2,4-dimethylcyclohex-3-ene-1-carbaldehyde [7] dimethylcyclohex-3-ene-1-carbaldehyde [8] Dimethylcyclohex-3-ene-1-carbaldehyde [9] 1,2,4(or 1,3,5)-trimethylcyclohex-3-ene-1-carbaldehyde [10] 1,3,4-trimethylcyclohex-3-ene-1-carbaldehyde [11] 2,2,4-trimethylcyclohex-3-ene-1-carbaldehyde [12] 2,4,6-trimethylcyclohex-3-enecarbaldehyde [13] isocyclocitral [14] 3,5,6-trimethylcyclohex-3-ene-1-carbaldehyde [15] 4,6,6-trimethylcyclohex-3-ene-1-carbaldehyde [16] | 268-264-1 [1] 252-395-6 [2] - [3] 268-263-6 [4] 267-186-5 [5] 253-139-6 [6] - [7] 248-742-6 [8] 272-113-5 [9] 276-055-1 [10] - [11] - [12] 215-833-7 [13] 215-638-7 [14] 266-810-3 [15] - [16] | 68039-49-6 [1] 35145-02-9 [2] 6975-94-6 [3] 68039-48-5 [4] 67801-65-4 [5] 36635-35-5 [6] - [7] 27939-60-2 [8] 68737-61-1 [9] 71832-78-5 [10] 40702-26-9 [11] 1726-47-2 [12] 1423-46-7 [13] 1335-66-6 [14] 67634-07-5 [15] 6754-27-4 [16] | Skin Sens. 1 | H317 | GHS07 Wng | H317 | |||
| Index No 606-157-00-7CAS 18402-84-1 | 606-157-00-7 | (3E)-dec-3-en-2-one | — | 18402-84-1 | Acute Tox. 4 Asp. Tox. 1 Skin Irrit. 2 Aquatic Chronic 2 | H332 H304 H315 H411 | GHS07 GHS08 GHS09 Dgr | H332 H304 H315 H411 | EUH071 | inhalation: ATE = 1,5 mg/L (dusts or mists) | |
| Index No 606-158-00-2CAS 119344-86-4EC 438-340-0 | 606-158-00-2 | 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one | 438-340-0 | 119344-86-4 | Repr. 1B Aquatic Acute 1 Aquatic Chronic 1 | H360Df H400 H410 | GHS08 GHS09 Dgr | H360Df H410 | M = 1 M = 1 | ||
| Index No 607-770-00-2CAS 26761-45-5EC 247-979-2 | 607-770-00-2 | 2,3-epoxypropyl neodecanoate | 247-979-2 | 26761-45-5 | Muta. 2 Skin Sens. 1A | H341 H317 | GHS08 GHS07 Wng | H341 H317 | Skin Sens. 1A; H317: C ≥ 0,001 % | ||
| Index No 607-771-00-8CAS 177406-68-7 | 607-771-00-8 | benthiavalicarb-isopropyl (ISO); isopropyl [(S)-1-{[(R)-1-(6-fluoro-1,3-benzothiazol-2-yl)ethyl]carbamoyl}-2-methylpropyl]carbamate | — | 177406-68-7 | Carc. 1B Repr. 2 Skin Sens. 1 Aquatic Chronic 2 | H350 H361fd H317 H411 | GHS08 GHS07 GHS09 Dgr | H350 H361fd H317 H411 | |||
| Index No 607-772-00-3CAS 6259-76-3EC 228-408-6 | 607-772-00-3 | hexyl salicylate | 228-408-6 | 6259-76-3 | Repr. 2 Skin Sens. 1 | H361d H317 | GHS08 GHS07 Wng | H361d H317 | |||
| Index No 607-773-00-9CAS 2386-87-0EC 219-207-4 | 607-773-00-9 | 7-oxabicyclo[4.1.0]hept-3-ylmethyl 7-oxabicyclo[4.1.0]heptane-3-carboxylate | 219-207-4 | 2386-87-0 | Muta. 2 STOT RE 2 Skin Sens. 1 | H341 H373 (nasal cavity) H317 | GHS08 GHS07 Wng | H341 H373 (nasal cavity) H317 | |||
| Index No 607-774-00-4CAS 100556-82-9CAS 17095-24-8EC 241-164-5 | 607-774-00-4 | tetrasodium 4-amino-5-hydroxy-3,6-bis[[4-[[2-(sulphonatooxy)ethyl]sulphonyl]phenyl]azo]naphthalene-2,7-disulphonate [1] Reaction products of 4-amino-5-hydroxynaphthalene-2,7-disulfonic acid, coupled twice with diazotized 2-[(4-aminophenyl)sulfonyl]ethyl hydrogen sulfate, sodium salts [2] disodium 4-amino-5-hydroxy-3,6-bis{[4-(vinylsulfonyl) phenyl]diazenyl}naphthalene-2,7-disulfonate [3] | 241-164-5 [1] - [2] - [3] | 17095-24-8 [1] - [2] 100556-82-9 [3] | Resp. Sens. 1A Skin Sens. 1 | H334 H317 | GHS08 Dgr | H334 H317 | |||
| Index No 607-775-00-XCAS 52556-42-0EC 258-004-5 | 607-775-00-X | Sodium 3-(allyloxy)-2-hydroxypropanesulphonate | 258-004-5 | 52556-42-0 | Repr. 1B Eye Dam. 1 | H360F H318 | GHS08 GHS05 Dgr | H360F H318 | |||
| Index No 609-074-00-4CAS 89-61-2EC 201-923-3 | 609-074-00-4 | 1,4-dichloro-2-nitrobenzene | 201-923-3 | 89-61-2 | Carc. 1B | H350 | GHS08 Dgr | H350 | |||
| Index No 611-182-00-1CAS 68516-81-4EC 271-183-4 | 611-182-00-1 | 2-[ethyl[3-methyl-4-[(5-nitrothiazol-2-yl)azo]phenyl]amino]ethanol | 271-183-4 | 68516-81-4 | Skin Sens. 1A | H317 | GHS07 Wng | H317 | Skin Sens. 1A; H317: C ≥ 0,001 % | ||
| Index No 612-299-00-0CAS 67306-00-7 | 612-299-00-0 | fenpropidin (ISO); (R,S)-1-[3-(4-tert-butylphenyl)-2-methylpropyl]piperidine | — | 67306-00-7 | Repr. 2 Acute Tox. 4 Acute Tox. 4 STOT SE 3 STOT SE 3 STOT RE 2 Skin Irrit. 2 Eye Dam. 1 Skin Sens. 1 Aquatic Acute 1 Aquatic Chronic 1 | H361d H332 H302 H335 H336 H373 (nervous system, eyes, lungs) H315 H318 H317 H400 H410 | GHS08 GHS07 GHS05 GHS09 Dgr | H361d H332 H302 H335 H336 H373 (nervous system, eyes, lungs) H315 H318 H317 H410 | Inhalation: ATE = 1,2 mg/L (dusts or mists) oral: ATE = 1330 mg/kg bw M = 1000 M = 10000 | ||
| Index No 613-350-00-XCAS 95-14-7EC 202-394-1 | 613-350-00-X | 1H-benzotriazole | 202-394-1 | 95-14-7 | Aquatic Chronic 2 | H411 | GHS09 Wng | H411 | |||
| Index No 613-351-00-5CAS 29385-43-1EC 249-596-6 | 613-351-00-5 | methyl-1H-benzotriazole | 249-596-6 | 29385-43-1 | Aquatic Chronic 2 | H411 | GHS09 Wng | H411 | |||
| Index No 616-243-00-6CAS 110-26-9EC 203-750-9 | 616-243-00-6 | N,N'-methylenediacrylamide | 203-750-9 | 110-26-9 | Muta. 1B | H340 | GHS08 Dgr | H340 | |||
| Index No 617-024-00-8CAS 3006-82-4EC 221-110-7 | 617-024-00-8 | tert-butyl 2-ethylperoxyhexanoate | 221-110-7 | 3006-82-4 | Repr. 1B Skin Sens. 1 | H360FD H317 | GHS08 GHS07 Dgr | H360FD H317 | |||
14 entries amended
| Identifiers | Version | Index No | Chemical name | EC No | CAS No | Classification | Labelling | Specific Conc. Limits, M-factors and ATEs | Notes | |||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Hazard Class and Category Code(s) | Hazard statement Code(s) | Pictogram, Signal Word Code(s) | Hazard statement Code(s) | Suppl. Hazard statement Code(s) | ||||||||
| Index No 005-005-00-1CAS 121-43-7EC 204-468-9 | Before | 005-005-00-1 | trimethyl borate | 204-468-9 | 121-43-7 | Flam. Liq. 3
Acute Tox. | H226 H312 | GHS02
GHS07
| H226 H312 | |||
| After | 005-005-00-1 | trimethyl borate | 204-468-9 | 121-43-7 | Flam. Liq. 3 Repr. 1B Acute Tox. 4* | H226 H360FD H312 | GHS02 GHS08 GHS07 Dgr | H226 H360FD H312 | 11 | |||
| Index No 016-022-00-9CAS 75-08-1EC 200-837-3 | Before | 016-022-00-9 | ethanethiol; ethyl mercaptan | 200-837-3 | 75-08-1 | Flam. Liq. | GHS02
| |||||
| After | 016-022-00-9 | ethanethiol; ethyl mercaptan | 200-837-3 | 75-08-1 | Flam. Liq. 1 Acute Tox. 3 Acute Tox. 4 Aquatic Acute 1 Aquatic Chronic 1 | H224 H331 H302 H400 H410 | GHS02 GHS06 GHS09 Dgr | H224 H331 H302 H410 | inhalation: ATE = 7,1 mg/L (vapours) oral: ATE = 680 mg/kg bw | |||
| Index No 029-019-01-X | Before | 029-019-01-X | copper flakes (coated with aliphatic acid) | Acute Tox. 3 Acute Tox. 4 Eye Irrit. 2 Aquatic Acute 1 Aquatic Chronic 1 | H331 H302 H319 H400 H410 | GHS06 GHS09 Dgr | H331 H302 H319 H410 | inhalation: ATE = 0,733 mg/l (dusts or mists)
oral: ATE = 500 mg/kg bw
M = 10
M = | ||||
| After | 029-019-01-X | copper flakes (coated with aliphatic acid) | Acute Tox. 3 Acute Tox. 4 Eye Irrit. 2 Aquatic Acute 1 Aquatic Chronic 1 | H331 H302 H319 H400 H410 | GHS06 GHS09 Dgr | H331 H302 H319 H410 | inhalation: ATE = 0,733 mg/l (dusts or mists) oral: ATE = 500 mg/kg bw M = 10 M = 1 | |||||
| Index No 601-037-00-0CAS 110-54-3EC 203-777-6 | Before | 601-037-00-0 | n-hexane | 203-777-6 | 110-54-3 | Flam. Liq. 2
Repr. 2
Asp. Tox. 1
STOT RE | H225
| GHS02 GHS08 GHS07 GHS09 Dgr | H225
| |||
| After | 601-037-00-0 | n-hexane | 203-777-6 | 110-54-3 | Flam. Liq. 2 Repr. 2 Asp. Tox. 1 STOT SE 3 STOT RE 1 Skin Irrit. 2 Aquatic Chronic 2 | H225 H361f*** H304 H336 H372 (nervous system) H315 H411 | GHS02 GHS08 GHS07 GHS09 Dgr | H225 H361f*** H304 H336 H372 (nervous system) H315 H411 | ||||
| Index No 604-020-00-6CAS 90-43-7EC 201-993-5 | Before | 604-020-00-6 | 201-993-5 | 90-43-7 | Eye | GHS07
GHS09
| ||||||
| After | 604-020-00-6 | biphenyl-2-ol; 2-phenylphenol; 2-hydroxybiphenyl | 201-993-5 | 90-43-7 | Carc. 2 Skin Corr. 1 Eye Dam. 1 Skin Sens. 1B Aquatic Acute 1Aquatic Chronic 1 | H351 H314 H318 H317 H400H410 | GHS08 GHS05 GHS07 GHS09 Dgr | H351 H314 H317 H410 | M = 1 M = 1 | |||
| Index No 605-001-00-5CAS 50-00-0EC 200-001-8 | Before | 605-001-00-5 | formaldehyde | 200-001-8 | 50-00-0 | Carc. 1B Muta. 2
Acute Tox. | H350
H341
| GHS08 GHS06 GHS05 Dgr | H350
H341
| B, | ||
| After | 605-001-00-5 | formaldehyde … % | 200-001-8 | 50-00-0 | Carc. 1B Muta. 2 Acute Tox. 2 Acute Tox. 4 Skin Corr. 1B Skin Sens. 1A | H350 H341 H330 H302 H314 H317 | GHS08 GHS06 GHS05 Dgr | H350 H341 H330 H302 H314 H317 | EUH071 | inhalation: ATE = 100 ppmV (gases) oral: ATE = 500 mg/kg bw STOT SE 3; H335: C ≥ 5 % Skin Corr. 1B; H314: C ≥ 25 % Skin Irrit. 2; H315: 5 % ≤ C < 25 % Eye Irrit. 2; H319: 5 % ≤ C < 25 % | B, D, F | |
| Index No 607-001-00-0CAS 64-18-6EC 200-579-1 | Before | 607-001-00-0 | formic acid … % | 200-579-1 | 64-18-6 | Skin Corr. 1A | H314 | GHS05 Dgr | H314 | Skin Corr. 1A; H314: C ≥ 90 % Skin Corr. 1B; | B | |
| After | 607-001-00-0 | formic acid … % | 200-579-1 | 64-18-6 | Flam. Liq. 3 Met. Corr. 1 Acute Tox. 3 Acute Tox. 4 Skin Corr. 1AEye Dam. 1 | H226 H290 H331 H302 H314H318 | GHS02 GHS05 GHS06 Dgr | H226 H290 H331 H302 H314 | EUH071 | inhalation: ATE = 7,4 mg/L (vapours) oral: ATE = 500 mg/kg bw Flam. Liq. 3; H226: C > 85 % Skin Corr. 1A; H314: C ≥ 90 % Skin Corr. 1B; 314: 10 % ≤ C < 90 % Skin Irrit. 2; H315: 2 % ≤ C < 10 % Eye Dam. 1; H318: C ≥ 10 % Eye Irrit. 2; H319: 2 %≤ C < 10 % | B | |
| Index No 607-043-00-XCAS 1918-00-9EC 217-635-6 | Before | 607-043-00-X | dicamba (ISO); 2,5-dichloro-6-methoxybenzoic acid; 3,6-dichloro-2-methoxybenzoic acid | 217-635-6 | 1918-00-9 | Acute Tox. 4 | H302
H318
| GHS05
| H302
H318
| |||
| After | 607-043-00-X | dicamba (ISO); 2,5-dichloro-6-methoxybenzoic acid; 3,6-dichloro-2-methoxybenzoic acid | 217-635-6 | 1918-00-9 | Acute Tox. 4 Acute Tox. 4 STOT SE 3 STOT SE 3 Eye Dam. 1 Aquatic Acute 1 Aquatic Chronic 2 | H332 H302 H335 H336 H318 H400 H411 | GHS07 GHS05 GHS09 Dgr | H332 H302 H335 H336 H318 H410 | inhalation: ATE = 4,0 mg/L (dusts or mists) oral: ATE = 1500 mg/kg bw M = 1 | |||
| Index No 607-094-00-8CAS 79-21-0EC 201-186-8 | Before | 607-094-00-8 | peracetic acid | 201-186-8 | 79-21-0 | GHS02
GHS05
| ||||||
| After | 607-094-00-8 | peracetic acid … % | 201-186-8 | 79-21-0 | Org. Perox. D Acute Tox. 2 Acute Tox. 2 Acute Tox. 3 Skin Corr. 1A Aquatic Acute 1Aquatic Chronic 1 | H242 H330 H310 H301 H314 H400H410 | GHS02 GHS06 GHS05 GHS09 Dgr | H242 H330 H310 H301 H314 H410 | EUH071 | inhalation: ATE = 0,2 mg/L (dusts or mists) dermal: ATE = 60 mg/kg bw oral: ATE = 80 mg/kg bw STOT SE 3; H335: C ≥ 1 %M = 10 M = 100 | B, D, T | |
| Index No 607-198-00-3CAS 121-79-9EC 204-498-2 | Before | 607-198-00-3 | propyl 3,4,5-trihydroxybenzoate | 204-498-2 | 121-79-9 | Acute Tox. 4 | H302 H317 | GHS07 Wng | H302 H317 | |||
| After | 607-198-00-3 | propyl 3,4,5-trihydroxybenzoate | 204-498-2 | 121-79-9 | Acute Tox. 4 Skin Sens. 1Aquatic Acute 1 Aquatic Chronic 1 | H302 H317H400 H410 | GHS07 GHS09 Wng | H302 H317H410 | oral: ATE = 1700 mg/kg bw M = 1 M = 1 | |||
| Index No 607-432-00-4CAS 178961-20-1CAS 87392-12-9 | Before | 607-432-00-4 | 87392-12-9 | Skin Sens. 1 Aquatic Acute 1 Aquatic Chronic 1 | H317 H400 H410 | GHS07 GHS09 Wng | H317 H410 | |||||
| After | 607-432-00-4 | S-metolachlor (ISO); 2-chloro-N-(2-ethyl-6-methylphenyl)-N-[(2S)-1-methoxypropan-2-yl]acetamide; (RaSa)-2-chloro-N-(6-ethyl-o-tolyl)-N-[(1S)-2-methoxy-1-methylethyl]acetamide [contains 80-100 % 2-chloro-N-(2-ethyl-6-methylphenyl)-N-[(2S)-1-methoxypropan-2-yl]acetamide and 0-20 % 2-chloro-N-(2-ethyl-6-methylphenyl)-N-[(2R)-1-methoxypropan-2-yl]acetamide] | — | 87392-12-9 | Carc. 2 Skin Sens. 1 Aquatic Acute 1 Aquatic Chronic 1 | H351 H317 H400 H410 | GHS08 GHS07 GHS09 Wng | H351 H317 H410 | EUH066 | M = 10 M = 10 | ||
| Index No 613-272-00-6CAS 175013-18-0 | Before | 613-272-00-6 | pyraclostrobin (ISO);
methyl | — | Acute Tox. 3 | H331 H315 H400 H410 | GHS06 GHS09 Dgr | H331 H315 H410 | ||||
| After | 613-272-00-6 | pyraclostrobin (ISO); methyl N-(2-{[1-(4-chlorophenyl)-1H-pyrazol-3-yl]oxymethyl}phenyl) N-methoxy carbamate | — | 175013-18-0 | Repr. 2 Acute Tox. 3 Acute Tox. 4 STOT SE 3 STOT RE 2 Skin Irrit. 2 Aquatic Acute 1 Aquatic Chronic 1 | H361d H331 H302 H335 H373 (liver, gastrointestinal tract, nasal cavity) H315 H400 H410 | GHS08 GHS06 GHS09 Dgr | H361d H331 H302 H335 H373 (liver, gastrointestinal tract, nasal cavity) H315 H410 | inhalation: ATE = 0,58 mg/L (dusts or mists) oral: ATE = 450 mg/kg bw M = 100 M = 100 | |||
| Index No 616-127-00-5EC 430-050-2 | Before | 616-127-00-5 | reaction mass | 430-050-2 | Skin Sens. 1
Aquatic Chronic | H317
| GHS07 GHS09 Wng | H317
| ||||
| After | 616-127-00-5 | reaction mass of N,N'-ethane-1,2-diylbis(decanamide) and 12-hydroxy-N-[2-[(1-oxodecyl)amino]ethyl]octadecanamide and N,N'-ethane-1,2-diylbis(12-hydroxyoctadecanamide) [1] reaction mass of N,N'-ethane-1,2-diylbis(decanamide) and 12-hydroxy-N-[2-[(1-oxodecyl)amino]ethyl]octadecanamide [2] | 430-050-2[1] - [2] | - [1] - [2] | Skin Sens. 1 Aquatic Acute 1 Aquatic Chronic 1 | H317 H400 H410 | GHS07 GHS09 Wng | H317 H410 | M = 100 M = 10 | |||
| Index No 617-008-00-0CAS 94-36-0EC 202-327-6 | Before | 617-008-00-0 | dibenzoyl peroxide; benzoyl peroxide | 202-327-6 | 94-36-0 | Org. Perox. B Eye Irrit. 2 Skin Sens. 1 | H241 H319 H317 | GHS01 GHS02 GHS07 Dgr | H241 H319 H317 | |||
| After | 617-008-00-0 | dibenzoyl peroxide; benzoyl peroxide | 202-327-6 | 94-36-0 | Org. Perox. B Eye Irrit. 2 Skin Sens. 1Aquatic Acute 1 Aquatic Chronic 1 | H241 H319 H317H400 H410 | GHS01 GHS02 GHS07 GHS09 Dgr | H241 H319 H317H410 | M = 10 M = 10 | |||
Text from EUR-Lex, before and after
Previous version, in force 1 September 2025 02008R1272-20250901 → this version, in force 1 May 2026 02008R1272-20260501
compared line by line: this provision is too large to compare word by word, so a marked line is a line that changed somewhere
ANNEX VI
Harmonised classification and labelling for certain hazardous substances
Part 1 of this Annex provides an introduction to the list of harmonised classification and labelling, including information listed for each entry and related classifications and hazard statements in Table 3.
… 466 unchanged lines …
Dgr H250
H314 A
005-005-00-1 trimethyl borate 204-468-9 121-43-7 Flam. Liq. 3
Acute Tox. 4 * H226 Repr. 1B
Acute Tox. 4* H226
H360FD
H312 GHS02
GHS08
GHS07
Wng H226
H312 005-006-00-7 dibutyltin hydrogen borate 401-040-5 75113-37-0 Repr. 1B Dgr H226
H360FD
H312 11
005-006-00-7 dibutyltin hydrogen borate 401-040-5 75113-37-0 Repr. 1B
Muta. 2
STOT RE 1
Acute Tox. 4 *
… 250 unchanged lines …
disodium octaborate tetrahydrate [2] 234-541-0 [1]
234-541-0 [2] 12008-41-2 [1]
12280-03-4 [2] Repr. 1B H360FD GHS08
Dgr H360FD 006-001-00-2 carbon monoxide 211-128-3 630-08-0 Flam. Gas 1 Dgr H360FD 005-023-00-X perboric acid (H3BO2(O2)), monosodium salt trihydrate [1]
perboric acid, sodium salt, tetrahydrate [2]
perboric acid (HBO(O2)), sodium salt, tetrahydrate [3] sodium peroxoborate, hexahydrate [4] 239-172-9 [1]
234-390-0 [2]
- [3]
- [4] 13517-20-9 [1]
37244-98-7 [2]
10486-00-7 [3]
- [4] Repr. 1B
Acute Tox. 4
STOT SE 3
Eye Dam. 1 H360FD
H332
H335
H318 GHS08
GHS05
GHS07
Dgr H360FD
H332
H335
H318 inhalation: ATE = 1,2 mg/L (dusts or mists)
Eye Dam. 1; H318: C ≥ 36 %
Eye Irrit. 2; H319: 22 % ≤ C < 36 % 11
005-024-00-5 sodium peroxometaborate 231-556-4 7632-04-4 Ox. Sol. 2
Repr. 1B
Acute Tox. 3
Acute Tox. 4
STOT SE 3
Eye Dam. 1 H272
H360FD
H331
H302
H335
H318 GHS03
GHS08
GHS06
GHS05
Dgr H272
H360FD
H331
H302
H335
H318 inhalation: ATE = 0,62 mg/L (dusts or mists)
oral: ATE = 730 mg/kg bw
Eye Dam. 1; H318:
C ≥ 22 %
Eye Irrit. 2; H319: 14 % ≤ C < 22 % 11
006-001-00-2 carbon monoxide 211-128-3 630-08-0 Flam. Gas 1
Press. Gas
Repr. 1A
Acute Tox. 3 *
… 1,076 unchanged lines …
GHS09
Dgr H318
H334
H410 M=100 007-001-00-5 ammonia, anhydrous 231-635-3 7664-41-7 Flam. Gas 2 H410 M=100 006-104-00-2 multi-walled carbon tubes (synthetic graphite in tubular shape) with a geometric tube diameter range ≥ 30 nm to < 3 μm and a length ≥ 5 μm and aspect ratio > 3:1, including multi-walled carbon nanotubes, MWC(N)T — — Carc. 1B
STOT RE 1 H350i
H372 (lung)(inhalation) GHS08
Dgr H350i
H372 (lung)(inhalation) STOT RE 1; H372: C ≥ 1 %;
STOT RE 2; H373: 0,1 % ≤ C < 1 % 007-001-00-5 ammonia, anhydrous 231-635-3 7664-41-7 Flam. Gas 2
Press. Gas
Acute Tox. 3 *
Skin Corr. 1B
… 2,978 unchanged lines …
H331
H410 U
016-022-00-9 ethanethiol;
ethyl mercaptan 200-837-3 75-08-1 Flam. Liq. 2
Acute Tox. 4 * ethyl mercaptan 200-837-3 75-08-1 Flam. Liq. 1
Acute Tox. 3
Acute Tox. 4
Aquatic Acute 1
Aquatic Chronic 1 H225
H332 Aquatic Chronic 1 H224
H331
H302
H400
H410 GHS02
GHS07 GHS06
GHS09
Dgr H225
H332
H410 016-023-00-4 dimethyl sulphate 201-058-1 77-78-1 Carc. 1B Dgr H224
H331
H302
H410 inhalation: ATE = 7,1 mg/L (vapours)
oral: ATE = 680 mg/kg bw 016-023-00-4 dimethyl sulphate 201-058-1 77-78-1 Carc. 1B
Muta. 2
Acute Tox. 2 *
Acute Tox. 3 *
… 2,808 unchanged lines …
Wng H302
H410 oral: ATE = 500 mg/kg bw
M = 10
M = 10 029-019-01-X copper flakes (coated with aliphatic acid) — — Acute Tox. 3
Acute Tox. 4
Eye Irrit. 2
Aquatic Acute 1
Aquatic Chronic 1 H331 M = 10 029-019-01-X copper flakes (coated with aliphatic acid) Acute Tox. 3 Acute Tox. 4
Eye Irrit. 2 Aquatic Acute 1 Aquatic Chronic 1 H331
H302
H319
H400
H410 GHS06
GHS09
Dgr H331
H302
H319
H410 inhalation: ATE = 0,733 mg/l (dusts or mists)
oral: ATE = 500 mg/kg bw H410 inhalation: ATE = 0,733 mg/l (dusts or mists)
oral: ATE = 500 mg/kg bw
M = 10
M = 10 029-020-00-8 copper(II) carbonate—copper(II) hydroxide (1:1) 235-113-6 12069-69-1 Acute Tox. 4 M = 1 029-020-00-8 copper(II) carbonate—copper(II) hydroxide (1:1) 235-113-6 12069-69-1 Acute Tox. 4
Acute Tox. 4
Eye Irrit. 2
Aquatic Acute 1
… 79 unchanged lines …
H318
H410 oral: ATE = 360 mg/kg bw
M = 1
M = 1 030-001-00-1 zinc powder — zinc dust (pyrophoric) 231-175-3 7440-66-6 Water-react. 1 M = 1 029-026-00-0 copper [specific surface area > 0,67 mm2/mg] 231-159-6 7440-50-8 Aquatic Acute 1
Aquatic Chronic 1 H400
H410 GHS09
Wng H410 M = 10
M = 1 030-001-00-1 zinc powder — zinc dust (pyrophoric) 231-175-3 7440-66-6 Water-react. 1
Pyr. Sol. 1
Aquatic Acute 1
Aquatic Chronic 1 H260
… 386 unchanged lines …
H315
H318
H410 M = 100
M = 100 048-001-00-5 cadmium compounds, with the exception of cadmium sulphoselenide (xCdS.yCdSe), reaction mass of cadmium sulphide with zinc sulphide (xCdS.yZnS), reaction mass of cadmium sulphide with mercury sulphide (xCdS.yHgS), and those specified elsewhere in this Annex — — Acute Tox. 4 * M = 100 047-004-00-9 silver massive: [particle diameter ≥ 1 mm] 231-131-3 7440-22-4 Repr. 2
STOT RE 2 H361f
H373 (nervous system) GHS08
Wng H361f
H373 (nervous system) 047-005-00-4 silver powder: [particle diameter > 100 nm < 1 mm] 231-131-3 7440-22-4 Repr. 2
STOT RE 2
Aquatic Acute 1
Aquatic Chronic 1 H361f
H373 (nervous system)
H400
H410 GHS08
GHS09
Wng H361f
H373 (nervous system)
H410 M = 10
M = 10 047-006-00-X silver nano: [particle diameter > 1 nm ≤ 100 nm] 231-131-3 7440-22-4 Repr. 2
STOT RE 2
Aquatic Acute 1
Aquatic Chronic 1 H361f
H373 (nervous system)
H400
H410 GHS08
GHS09
Wng H361f
H373 (nervous system)
H410 M = 1000
M = 1000 048-001-00-5 cadmium compounds, with the exception of cadmium sulphoselenide (xCdS.yCdSe), reaction mass of cadmium sulphide with zinc sulphide (xCdS.yZnS), reaction mass of cadmium sulphide with mercury sulphide (xCdS.yHgS), and those specified elsewhere in this Annex — — Acute Tox. 4 *
Acute Tox. 4 *
Acute Tox. 4 *
Aquatic Acute 1
… 2,125 unchanged lines …
H410 601-037-00-0 n-hexane 203-777-6 110-54-3 Flam. Liq. 2
Repr. 2
Asp. Tox. 1
STOT RE 2 * STOT SE 3
STOT RE 1
Skin Irrit. 2
STOT SE 3
Aquatic Chronic 2 H225
H361f *** H304
H373 ** H361f***
H304
H336
H372 (nervous system)
H315
H336
H411 GHS02
GHS08
GHS07
GHS09
Dgr H225
H361f *** H304
H373 ** H315 H361f***
H304
H336
H411 STOT RE 2; H373: C ≥ 5 % 601-041-00-2 dibenz[a,h]anthracene 200-181-8 53-70-3 Carc. 1B H372 (nervous system)
H315
H411 601-041-00-2 dibenz[a,h]anthracene 200-181-8 53-70-3 Carc. 1B
Aquatic Acute 1
Aquatic Chronic 1 H350
H400
… 3,592 unchanged lines …
H410 GHS08
GHS09
Wng H373 (teeth, bones)
H410 M = 1 604-001-00-2 phenol; carbolic acid; monohydroxybenzene; phenylalcohol 203-632-7 108-95-2 Muta. 2 H410 M = 1 603-247-00-8 reaction mass of 1,3-dioxan-5-ol and 1,3-dioxolan-4-ylmethanol — — Repr. 1B H360Df GHS08
Dgr H360Df 604-001-00-2 phenol; carbolic acid; monohydroxybenzene; phenylalcohol 203-632-7 108-95-2 Muta. 2
Acute Tox. 3 * Acute Tox. 3 *
Acute Tox. 3 * STOT RE 2 *
Skin Corr. 1B H341
… 304 unchanged lines …
GHS09
Wng H302
H319
H410 604-020-00-6 2-phenylphenol (ISO)biphenyl-2-ol; 2-hydroxybiphenyl; 201-993-5 90-43-7 Eye Irrit. 2
STOT SE 3
Skin Irrit. 2
Aquatic Acute 1 H319
H335
H315
H400 GHS07 H410 604-020-00-6 biphenyl-2-ol; 2-phenylphenol; 2-hydroxybiphenyl 201-993-5 90-43-7 Carc. 2
Skin Corr. 1
Eye Dam. 1
Skin Sens. 1B
Aquatic Acute 1
Aquatic Chronic 1 H351
H314
H318
H317
H400
H410 GHS08
GHS05
GHS07
GHS09
Wng H319
H335
H315
H400 604-021-00-1 sodium 2-biphenylate; 2-phenylphenol, sodium salt 205-055-6 132-27-4 Acute Tox. 4 * STOT SE 3 Dgr H351
H314
H317
H410 M = 1
M = 1 604-021-00-1 sodium 2-biphenylate; 2-phenylphenol, sodium salt 205-055-6 132-27-4 Acute Tox. 4 * STOT SE 3
Skin Irrit. 2
Eye Dam. 1
Aquatic Acute 1 H302
… 541 unchanged lines …
Aquatic Chronic 1 H400
H410 GHS09
Wng H410 M = 1
M = 10 605-001-00-5 formaldehyde …% 200-001-8 50-00-0 Carc. 1B Muta. 2
Acute Tox. 3* Acute Tox. 3* Acute Tox. 3* M = 10 605-001-00-5 formaldehyde … % 200-001-8 50-00-0 Carc. 1B
Muta. 2
Acute Tox. 2
Acute Tox. 4
Skin Corr. 1B
Skin Sens. 1 H350 Skin Sens. 1A H350
H341
H301
H311
H331 H330
H302
H314
H317 GHS08
GHS06
GHS05
Dgr H350
H341
H301
H311
H331 H330
H302
H314
H317 *
Skin Corr. 1B; H314: C ≥25 % Skin Irrit. 2; H315: 5 % ≤C
< 25 %
Eye Irrit. 2; H319: 5 % ≤ C
<25 %
STOT SE 3; H335: C ≥ 5 % SkinSens.; H317: C ≥ 0,2 % B, D H317 EUH071 inhalation: ATE = 100 ppmV (gases)
oral: ATE = 500 mg/kg bw
STOT SE 3; H335: C ≥ 5 %
Skin Corr. 1B; H314: C ≥ 25 %
Skin Irrit. 2; H315: 5 % ≤ C < 25 %
Eye Irrit. 2; H319: 5 % ≤ C < 25 % B, D, F
605-002-00-0 1,3,5-trioxan; trioxymethylene 203-812-5 110-88-3 Flam. Sol. 1
Repr. 2
STOT SE 3 H228
… 310 unchanged lines …
31906-04-4 [2]
51414-25-6 [3] Skin Sens. 1A H317 GHS07
Wng H317 605-041-00-3 2-(4-tert-butylbenzyl)propionaldehyde 201-289-8 80-54-6 Repr. 1B H360Fd GHS08
Dgr H360Fd 606-001-00-8 acetone; propan-2-one; propanone 200-662-2 67-64-1 Flam. Liq. 2 Dgr H360Fd 605-042-00-9 α-methyl-1,3-benzodioxole-5-propionaldehyde [1]
(S)-α-methyl-1,3-benzodioxole-5-propionaldehyde;
(2S)-3-(1,3-benzodioxol-5-yl)-2-methylpropanal [2]
(R)-α-methyl-1,3-benzodioxole-5-propionaldehyde;
(2R)-3-(1,3-benzodioxol-5-yl)-2-methylpropanal [3] 214-881-6 [1]
- [2]
- [3] 1205-17-0 [1]
737776-68-0 [2]
737776-59-9 [3] Skin Sens. 1B H317 GHS07
Wng H317 605-043-00-4 2,4-dimethylcyclohex-3-ene-1-carbaldehyde [1]
(1α,2α,5α)-2,5-dimethylcyclohex-3-ene-1-carbaldehyde [2]
2,6-dimethylcyclohex-3-ene-1-carbaldehyde [3]
3,5-dimethylcyclohex-3-ene-1-carbaldehyde [4]
3,6-dimethylcyclohex-3-ene-1-carbaldehyde [5]
4,6-dimethylcyclohex-3-ene-1-carbaldehyde [6]
reaction mass of 3,5-dimethylcyclohex-3-ene-1-carbaldehyde and 2,4-dimethylcyclohex-3-ene-1-carbaldehyde [7]
dimethylcyclohex-3-ene-1-carbaldehyde [8]
Dimethylcyclohex-3-ene-1-carbaldehyde [9]
1,2,4(or 1,3,5)-trimethylcyclohex-3-ene-1-carbaldehyde [10]
1,3,4-trimethylcyclohex-3-ene-1-carbaldehyde [11]
2,2,4-trimethylcyclohex-3-ene-1-carbaldehyde [12]
2,4,6-trimethylcyclohex-3-enecarbaldehyde [13]
isocyclocitral [14]
3,5,6-trimethylcyclohex-3-ene-1-carbaldehyde [15]
4,6,6-trimethylcyclohex-3-ene-1-carbaldehyde [16] 268-264-1 [1]
252-395-6 [2]
- [3]
268-263-6 [4]
267-186-5 [5]
253-139-6 [6]
- [7]
248-742-6 [8]
272-113-5 [9]
276-055-1 [10]
- [11]
- [12]
215-833-7 [13]
215-638-7 [14]
266-810-3 [15]
- [16] 68039-49-6 [1]
35145-02-9 [2]
6975-94-6 [3]
68039-48-5 [4]
67801-65-4 [5]
36635-35-5 [6]
- [7]
27939-60-2 [8]
68737-61-1 [9]
71832-78-5 [10]
40702-26-9 [11]
1726-47-2 [12]
1423-46-7 [13]
1335-66-6 [14]
67634-07-5 [15]
6754-27-4 [16] Skin Sens. 1 H317 GHS07
Wng H317 606-001-00-8 acetone; propan-2-one; propanone 200-662-2 67-64-1 Flam. Liq. 2
Eye Irrit. 2
STOT SE 3 H225
H319
… 870 unchanged lines …
M = 10 606-155-00-6 cinnamaldehyde; 3-phenylprop-2-enal;
cinnamic aldehyde; cinnamal; [1]
(2E)-3-phenylprop-2-enal [2] 203-213-9 [1] - [2] 104-55-2 [1] 14371-10-9 [2] Skin Sens. 1A H317 GHS07
Wng H317 Skin Sens. 1A; H317: C ≥ 0,01 % 607-001-00-0 formic acid … % 200-579-1 64-18-6 Skin Corr. 1A H314 GHS05
Dgr H314 Skin Corr. 1A; H314: C ≥ 90 % Skin Corr. 1B; H314: 10 % ≤ C < 90 %
Skin Irrit. 2; H315: 2 % ≤C
< 10 %
Eye Irrit. 2; H319: 2 %≤
<10 % B Wng H317 Skin Sens. 1A; H317: C ≥ 0,01 % 606-157-00-7 (3E)-dec-3-en-2-one — 18402-84-1 Acute Tox. 4
Asp. Tox. 1
Skin Irrit. 2
Aquatic Chronic 2 H332
H304
H315
H411 GHS07
GHS08
GHS09
Dgr H332
H304
H315
H411 EUH071 inhalation: ATE = 1,5 mg/L (dusts or mists) 606-158-00-2 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(morpholin-4-yl)phenyl]butan-1-one 438-340-0 119344-86-4 Repr. 1B
Aquatic Acute 1
Aquatic Chronic 1 H360Df
H400
H410 GHS08
GHS09
Dgr H360Df
H410 M = 1
M = 1 607-001-00-0 formic acid … % 200-579-1 64-18-6 Flam. Liq. 3
Met. Corr. 1
Acute Tox. 3
Acute Tox. 4
Skin Corr. 1A
Eye Dam. 1 H226
H290
H331
H302
H314
H318 GHS02
GHS05
GHS06
Dgr H226
H290
H331
H302
H314 EUH071 inhalation: ATE = 7,4 mg/L (vapours)
oral: ATE = 500 mg/kg bw
Flam. Liq. 3; H226: C > 85 %
Skin Corr. 1A; H314: C ≥ 90 %
Skin Corr. 1B; 314: 10 % ≤ C < 90 %
Skin Irrit. 2; H315: 2 % ≤ C < 10 %
Eye Dam. 1; H318: C ≥ 10 %
Eye Irrit. 2; H319: 2 % ≤ C < 10 % B
607-002-00-6 acetic acid … % 200-580-7 64-19-7 Flam. Liq. 3
Skin Corr. 1A H226
H314 GHS02
… 412 unchanged lines …
H335
H315
H410 A
607-043-00-X dicamba (ISO); 2,5-dichloro-6-methoxybenzoic acid; 3,6-dichloro-2-methoxybenzoic acid 217-635-6 1918-00-9 Acute Tox. 4 * 607-043-00-X dicamba (ISO); 2,5-dichloro-6-methoxybenzoic acid; 3,6-dichloro-2-methoxybenzoic acid 217-635-6 1918-00-9 Acute Tox. 4
Acute Tox. 4
STOT SE 3
STOT SE 3
Eye Dam. 1
Aquatic Chronic 3 H302 Aquatic Acute 1
Aquatic Chronic 2 H332
H302
H335
H336
H318
H412 GHS05
GHS07
Dgr H302 H400
H411 GHS07
GHS05
GHS09
Dgr H332
H302
H335
H336
H318
H412 607-044-00-5 3,6-dichloro-o-anisic acid, compound with dimethylamine (1:1); [1] potassium 3,6-dichloro-o-anisate[2] 218-951-7 [1] H410 inhalation: ATE = 4,0 mg/L (dusts or mists)
oral: ATE = 1500 mg/kg bw
M = 1 607-044-00-5 3,6-dichloro-o-anisic acid, compound with dimethylamine (1:1); [1] potassium 3,6-dichloro-o-anisate[2] 218-951-7 [1]
233-002-7 [2] 2300-66-5 [1]
10007-85-9 [2] Eye Irrit. 2
Aquatic Chronic 3 H319
… 442 unchanged lines …
GHS05
Dgr H225
H314 EUH014 B D
607-094-00-8 peracetic acid . . . % 201-186-8 79-21-0 Flam. Liq. 3
Org. Perox. D **** Acute Tox. 4 *
Acute Tox. 4 *
Acute Tox. 4 *
Skin Corr. 1A Aquatic Acute 1 H226
H242
H332
H312
H302 607-094-00-8 peracetic acid … % 201-186-8 79-21-0 Org. Perox. D
Acute Tox. 2
Acute Tox. 2
Acute Tox. 3
Skin Corr. 1A
Aquatic Acute 1
Aquatic Chronic 1 H242
H330
H310
H301
H314
H400 GHS02 H400
H410 GHS02
GHS06
GHS05
GHS07
GHS09
Dgr H226
H242
H332
H312
H302 Dgr H242
H330
H310
H301
H314
H400 *
STOT SE 3; H335: C ≥ 1 % B D H410 EUH071 inhalation: ATE = 0,2 mg/L (dusts or mists)
dermal: ATE = 60 mg/kg bw
oral: ATE = 80 mg/kg bw
STOT SE 3; H335: C ≥ 1 %
M = 10
M = 100 B, D, T
607-095-00-3 maleic acid 203-742-5 110-16-7 Acute Tox. 4 *
Eye Irrit. 2
STOT SE 3
… 811 unchanged lines …
H412 GHS07
Wng H315
H319
H412 607-198-00-3 propyl 3,4,5-trihydroxybenzoate 204-498-2 121-79-9 Acute Tox. 4 *
Skin Sens. 1 H302
H317 GHS07 H412 607-198-00-3 propyl 3,4,5-trihydroxybenzoate 204-498-2 121-79-9 Acute Tox. 4
Skin Sens. 1
Aquatic Acute 1
Aquatic Chronic 1 H302
H317
H400
H410 GHS07
GHS09
Wng H302
H317 607-199-00-9 octyl 3,4,5-trihydroxybenzoate 213-853-0 1034-01-1 Acute Tox. 4 * H317
H410 oral: ATE = 1700 mg/kg bw
M = 1
M = 1 607-199-00-9 octyl 3,4,5-trihydroxybenzoate 213-853-0 1034-01-1 Acute Tox. 4 *
Skin Sens. 1 H302
H317 GHS07
Wng H302
… 1,428 unchanged lines …
GHS09
Dgr H331
H302
H410 607-432-00-4 S-metolachlor; reaction mass of (S)-2-chloro-N-(2-ethyl-6-methyl-phenyl)-N-(2-methoxy-1-methyl-ethyl)-acetamide (80-100 %); [1] (R)-2-chloro-N-(2-ethyl-6-methyl-phenyl)-N-(2-methoxy-1-methyl-ethyl)-acetamide (0-20 %) [2] -[1]
-[2] 87392-12-9 [1]
178961-20-1 [2] Skin Sens. 1 H410 607-432-00-4 S-metolachlor (ISO); 2-chloro-N-(2-ethyl-6-methylphenyl)-N-[(2S)-1-methoxypropan-2-yl]acetamide; (RaSa)-2-chloro-N-(6-ethyl-o-tolyl)-N-[(1S)-2-methoxy-1-methylethyl]acetamide
[contains 80-100 % 2-chloro-N-(2-ethyl-6-methylphenyl)-N-[(2S)-1-methoxypropan-2-yl]acetamide and 0-20 % 2-chloro-N-(2-ethyl-6-methylphenyl)-N-[(2R)-1-methoxypropan-2-yl]acetamide] — 87392-12-9 Carc. 2
Skin Sens. 1
Aquatic Acute 1
Aquatic Chronic 1 H317 Aquatic Chronic 1 H351
H317
H400
H410 GHS07 H410 GHS08
GHS07
GHS09
Wng H317
H410 607-433-00-X cypermethrin cis/trans +/-80/20; (RS)-α-cyano-3-phenoxybenzyl (1RS;3RS; 1RS, 3SR)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate 257-842-9 52315-07-8 Acute Tox. 4 * STOT SE 3 Wng H351
H317
H410 EUH066 M = 10
M = 10 607-433-00-X cypermethrin cis/trans +/-80/20; (RS)-α-cyano-3-phenoxybenzyl (1RS;3RS; 1RS, 3SR)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate 257-842-9 52315-07-8 Acute Tox. 4 * STOT SE 3
Skin Irrit. 2
Skin Sens. 1
Aquatic Acute 1
… 1,739 unchanged lines …
H410 oral:
ATE = 1500 mg/kg bw
M = 1000
M = 1000 608-001-00-3 acetonitrile; cyanomethane 200-835-2 75-05-8 Flam. Liq. 2 M = 1000 607-770-00-2 2,3-epoxypropyl neodecanoate 247-979-2 26761-45-5 Muta. 2
Skin Sens. 1A H341
H317 GHS08
GHS07
Wng H341
H317 Skin Sens. 1A; H317: C ≥ 0,001 % 607-771-00-8 benthiavalicarb-isopropyl (ISO); isopropyl [(S)-1-{[(R)-1-(6-fluoro-1,3-benzothiazol-2-yl)ethyl]carbamoyl}-2-methylpropyl]carbamate — 177406-68-7 Carc. 1B
Repr. 2
Skin Sens. 1
Aquatic Chronic 2 H350
H361fd
H317
H411 GHS08
GHS07
GHS09
Dgr H350
H361fd
H317
H411 607-772-00-3 hexyl salicylate 228-408-6 6259-76-3 Repr. 2
Skin Sens. 1 H361d
H317 GHS08
GHS07
Wng H361d
H317 607-773-00-9 7-oxabicyclo[4.1.0]hept-3-ylmethyl 7-oxabicyclo[4.1.0]heptane-3-carboxylate 219-207-4 2386-87-0 Muta. 2
STOT RE 2
Skin Sens. 1 H341
H373 (nasal cavity)
H317 GHS08
GHS07
Wng H341
H373 (nasal cavity)
H317 607-774-00-4 tetrasodium 4-amino-5-hydroxy-3,6-bis[[4-[[2-(sulphonatooxy)ethyl]sulphonyl]phenyl]azo]naphthalene-2,7-disulphonate [1]
Reaction products of 4-amino-5-hydroxynaphthalene-2,7-disulfonic acid, coupled twice with diazotized 2-[(4-aminophenyl)sulfonyl]ethyl hydrogen sulfate, sodium salts [2]
disodium 4-amino-5-hydroxy-3,6-bis{[4-(vinylsulfonyl) phenyl]diazenyl}naphthalene-2,7-disulfonate [3] 241-164-5 [1]
- [2]
- [3] 17095-24-8 [1]
- [2]
100556-82-9 [3] Resp. Sens. 1A
Skin Sens. 1 H334
H317 GHS08
Dgr H334
H317 607-775-00-X Sodium 3-(allyloxy)-2-hydroxypropanesulphonate 258-004-5 52556-42-0 Repr. 1B
Eye Dam. 1 H360F
H318 GHS08
GHS05
Dgr H360F
H318 608-001-00-3 acetonitrile; cyanomethane 200-835-2 75-05-8 Flam. Liq. 2
Acute Tox. 4 * Acute Tox. 4 * Acute Tox. 4 *
Eye Irrit. 2 H225
H332
… 1,535 unchanged lines …
H302
H317
H412 609-073-00-9 lithium potassium sodium N,N''-bis{6-[7-[4-(4-chloro-1,3,5-triazin-2-yl)amino-4-(2-ureidophenylazo)]naphthalene-1,3,6-trisulfonato}-N'-(2-aminoethyl)piperazine 427-850-9 — Skin Sens. 1 H317 GHS07
Wng H317 610-001-00-3 trichloronitromethane; Wng H317 609-074-00-4 1,4-dichloro-2-nitrobenzene 201-923-3 89-61-2 Carc. 1B H350 GHS08
Dgr H350 610-001-00-3 trichloronitromethane;
chloropicrin 200-930-9 76-06-2 Acute Tox. 2 *
Acute Tox. 4 *
Eye Irrit. 2
… 1,021 unchanged lines …
H373 (liver)
H315
H318
H411 oral: ATE = 136 mg/kg bw 612-001-00-9 mono-methylamine; [1] H411 oral: ATE = 136 mg/kg bw 611-182-00-1 2-[ethyl[3-methyl-4-[(5-nitrothiazol-2-yl)azo]phenyl]amino]ethanol 271-183-4 68516-81-4 Skin Sens. 1A H317 GHS07
Wng H317 Skin Sens. 1A; H317: C ≥ 0,001 % 612-001-00-9 mono-methylamine; [1]
di-methylamine; [2]
tri-methylamine [3] 200-820-0 [1]
204-697-4 [2]
… 3,599 unchanged lines …
H317 GHS08
GHS07
Dgr H360FD
H317 613-001-00-1 ethyleneimine; aziridine 205-793-9 151-56-4 Flam. Liq. 2 H317 612-299-00-0 fenpropidin (ISO); (R,S)-1-[3-(4-tert-butylphenyl)-2-methylpropyl]piperidine — 67306-00-7 Repr. 2
Acute Tox. 4
Acute Tox. 4
STOT SE 3
STOT SE 3
STOT RE 2
Skin Irrit. 2
Eye Dam. 1
Skin Sens. 1
Aquatic Acute 1
Aquatic Chronic 1 H361d
H332
H302
H335
H336
H373 (nervous system, eyes, lungs)
H315
H318
H317
H400
H410 GHS08
GHS07
GHS05
GHS09
Dgr H361d
H332
H302
H335
H336
H373 (nervous system, eyes, lungs)
H315
H318
H317
H410 Inhalation: ATE = 1,2 mg/L (dusts or mists)
oral: ATE = 1330 mg/kg bw
M = 1000
M = 10000 613-001-00-1 ethyleneimine; aziridine 205-793-9 151-56-4 Flam. Liq. 2
Carc. 1B
Muta. 1B
Acute Tox. 2 *
… 2,219 unchanged lines …
H410 GHS07
GHS09
Wng H317
H410 M=10 613-272-00-6 pyraclostrobin (ISO);
methyl N-{2-[1-(4-chlorophenyl)-1H-pyrazol-3-yloxymethyl]phenyl}(N-methoxy)carbamate — — Acute Tox. 3 * H410 M=10 613-272-00-6 pyraclostrobin (ISO); methyl N-(2-{[1-(4-chlorophenyl)-1H-pyrazol-3-yl]oxymethyl}phenyl) N-methoxy carbamate — 175013-18-0 Repr. 2
Acute Tox. 3
Acute Tox. 4
STOT SE 3
STOT RE 2
Skin Irrit. 2
Aquatic Acute 1
Aquatic Chronic 1 H331 Aquatic Chronic 1 H361d
H331
H302
H335
H373 (liver, gastrointestinal tract, nasal cavity)
H315
H400
H410 GHS06 H410 GHS08
GHS06
GHS09
Dgr H331 Dgr H361d
H331
H302
H335
H373 (liver, gastrointestinal tract, nasal cavity)
H315
H410 M=100 613-273-00-1 tetrahydro-3-methyl-5-((2-phenylthio)thiazol-5-ylmethyl)-[4H]-1,3,5-oxadiazinan-4-ylidene-N-nitroamine 427-600-9 192439-46-6 Aquatic Chronic 2 H411 GHS09 H411 613-274-00-7 2,6-dichloro-1-fluoropyridiniumtetrafluoroborate 427-400-1 140623-89-8 Skin Corr. 1B H410 inhalation: ATE = 0,58 mg/L (dusts or mists)
oral: ATE = 450 mg/kg bw
M = 100
M = 100 613-273-00-1 tetrahydro-3-methyl-5-((2-phenylthio)thiazol-5-ylmethyl)-[4H]-1,3,5-oxadiazinan-4-ylidene-N-nitroamine 427-600-9 192439-46-6 Aquatic Chronic 2 H411 GHS09 H411 613-274-00-7 2,6-dichloro-1-fluoropyridiniumtetrafluoroborate 427-400-1 140623-89-8 Skin Corr. 1B
Acute Tox. 4 *
Skin Sens. 1
Aquatic Acute 1
… 732 unchanged lines …
Repr. 1B H350
H360Fd GHS08
Dgr H350
H360Fd 614-001-00-4 nicotine (ISO); H360Fd 613-350-00-X 1H-benzotriazole 202-394-1 95-14-7 Aquatic Chronic 2 H411 GHS09
Wng H411 613-351-00-5 methyl-1H-benzotriazole 249-596-6 29385-43-1 Aquatic Chronic 2 H411 GHS09
Wng H411 614-001-00-4 nicotine (ISO);
3-[(2S)-1-methylpyrrolidin-2-yl]pyridine 200-193-3 54-11-5 Acute Tox. 2
Acute Tox. 2
Acute Tox. 2
… 1,503 unchanged lines …
GHS07
Wng H302
H373**
H412 616-127-00-5 reaction mass of: N, N'-Ethane-1,2-diylbis(decanamide);
12-Hydroxy-N-[2-[1-oxydecyl)amino]ethyl]octadecanamide;
N, N'-Ethane-1,2-diylbis(12hydroxyoctadecanamide) 430-050-2 — Skin Sens. 1
Aquatic Chronic 2 H317
H411 GHS07 H412 616-127-00-5 reaction mass of N,N'-ethane-1,2-diylbis(decanamide) and 12-hydroxy-N-[2-[(1-oxodecyl)amino]ethyl]octadecanamide and N,N'-ethane-1,2-diylbis(12-hydroxyoctadecanamide) [1]
reaction mass of N,N'-ethane-1,2-diylbis(decanamide) and 12-hydroxy-N-[2-[(1-oxodecyl)amino]ethyl]octadecanamide [2] 430-050-2 [1]
- [2] - [1]
- [2] Skin Sens. 1
Aquatic Acute 1
Aquatic Chronic 1 H317
H400
H410 GHS07
GHS09
Wng H317
H411 616-128-00-0 N-(2-(1-allyl-4,5-dicyanoimidazol-2-ylazo)-5-(dipropylamino)phenyl)-acetamide 417-530-7 123590-00-1 Aquatic Chronic 4 H413 — H413 616-129-00-6 N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)isophthalamide 419-710-0 42774-15-2 Acute Tox. 4 * H410 M = 100
M = 10 616-128-00-0 N-(2-(1-allyl-4,5-dicyanoimidazol-2-ylazo)-5-(dipropylamino)phenyl)-acetamide 417-530-7 123590-00-1 Aquatic Chronic 4 H413 — H413 616-129-00-6 N,N'-bis(2,2,6,6-tetramethyl-4-piperidyl)isophthalamide 419-710-0 42774-15-2 Acute Tox. 4 *
Eye Irrit. 2 H302
H319 GHS07
Wng H302
… 590 unchanged lines …
GHS09
Wng H373 (blood system, thyroid)
H410 M = 1000
M = 1000 617-001-00-2 di-tert-butyl peroxide 203-733-6 110-05-4 Org. Perox. E Flam. Liq. 2 Muta. 2 H242 M = 1000 616-243-00-6 N,N'-methylenediacrylamide 203-750-9 110-26-9 Muta. 1B H340 GHS08
Dgr H340 617-001-00-2 di-tert-butyl peroxide 203-733-6 110-05-4 Org. Perox. E Flam. Liq. 2 Muta. 2 H242
H225
H341 GHS02
GHS08
… 70 unchanged lines …
GHS09
Wng H242
H315
H411 617-008-00-0 dibenzoyl peroxide;
benzoyl peroxide 202-327-6 94-36-0 Org. Perox. B H411 617-008-00-0 dibenzoyl peroxide; benzoyl peroxide 202-327-6 94-36-0 Org. Perox. B
Eye Irrit. 2
Skin Sens. 1 H241 Skin Sens. 1
Aquatic Acute 1
Aquatic Chronic 1 H241
H319
H317 GHS01 H317
H400
H410 GHS01
GHS02
GHS07
GHS09
Dgr H241
H319
H317 617-010-00-1 1-hydroperoxycyclohexyl 1-hydroxycyclohexyl peroxide; [1] H317
H410 M = 10
M = 10 617-010-00-1 1-hydroperoxycyclohexyl 1-hydroxycyclohexyl peroxide; [1]
1,1’-dioxybiscyclohexan-1-ol; [2]
cyclohexylidene hydroperoxide; [3]
cyclohexanone, peroxide [4] 201-091-1 [1]
… 139 unchanged lines …
H314
H317
H411 617-023-00-2 tert-butyl hydroperoxide 200-915-7 75-91-2 Muta. 2 H341 GHS08
Wng H341 647-001-00-8 glucosidase, β- 232-589-7 9001-22-3 Resp. Sens. 1 H334 GHS08 Wng H341 617-024-00-8 tert-butyl 2-ethylperoxyhexanoate 221-110-7 3006-82-4 Repr. 1B
Skin Sens. 1 H360FD
H317 GHS08
GHS07
Dgr H360FD
H317 647-001-00-8 glucosidase, β- 232-589-7 9001-22-3 Resp. Sens. 1 H334 GHS08
Dgr H334 647-002-00-3 cellulase 232-734-4 9012-54-8 Resp. Sens. 1 H334 GHS08
Dgr H334 647-003-00-9 cellobiohydrolase, exo- 253-465-9 37329-65-0 Resp. Sens. 1 H334 GHS08
Dgr H334 647-004-00-4 cellulases with the exception of those specified elsewhere in this Annex — — Resp. Sens. 1 H334 GHS08
… 24,737 unchanged lines …
S: 61 650-055-00-5 silver sodium zirconium hydrogenphosphate 422-570-3 155925-27-2 N; R50-53 N
R: 50/53
S: 60-61
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